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Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides

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Dmitry S. Novikov 1
Dmitry S. Novikov
,  , 
10.71267/mencom.7866
Published 2025-11-29
Communication , Volume 36, Issue 1, 18-20
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Abronina P. I. et al. Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 18-20.
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Abronina P. I., Novikov D. S., Zinin A. I., Kononov L. O. Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 18-20.
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TY - JOUR
DO - 10.71267/mencom.7866
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7866
TI - Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides
T2 - Mendeleev Communications
AU - Abronina, Polina I.
AU - Novikov, Dmitry S.
AU - Zinin, Alexander Ivanovich
AU - Kononov, Leonid Olegovich
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 18-20
IS - 1
VL - 36
ER -
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@article{2025_Abronina,
author = {Polina I. Abronina and Dmitry S. Novikov and Alexander Ivanovich Zinin and Leonid Olegovich Kononov},
title = {Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7866},
number = {1},
pages = {18--20},
doi = {10.71267/mencom.7866}
}
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Abronina, Polina I., et al. “Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 18-20. https://mendcomm.colab.ws/publications/10.71267/mencom.7866.
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Keywords

D-arabinofuranose
glycosylation
Janus aglycone
Mycobacterium tuberculosis.
silyl group

Abstract

A convergent synthesis of linear α-(1→5)-, β-(1→2)-linked octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides was performed using a [6+2] scheme. The octaarabinofuranoside was obtained as a 4-(2-azidoethoxy)phenyl glycoside which can be further converted to neoglycoconjugates that are important for the development of diagnostic tools.

Funders

Russian Science Foundation
21-73-20164-P

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