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Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor

Katherina S Shavelkina 1
Katherina S Shavelkina
, 
Sergei Sergeevich Bubenov 1
Sergei Sergeevich Bubenov
, 
Vadim Mikhailovich Popelensky 1
Vadim Mikhailovich Popelensky
, 
Kirill Alekseevich Cherednichenko 1, 2
Kirill Alekseevich Cherednichenko
, 
Alexander Alexandrovich Vinokurov 1
Alexander Alexandrovich Vinokurov
, 
Valeriya V Rybina 1
Valeriya V Rybina
, 
Sergey Gennadievich Dorofeev 1
Sergey Gennadievich Dorofeev
10.71267/mencom.8051
Published 28 July 2026 , received 26 March 2026
Communication , Volume 36, Issue 5, 617-619
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Shavelkina K. S. et al. Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 617-619.
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Shavelkina K. S., Bubenov S. S., Popelensky V. M., Cherednichenko K. A., Vinokurov A. A., Rybina V. V., Dorofeev S. G. Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 617-619.
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TY - JOUR
DO - 10.71267/mencom.8051
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8051
TI - Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor
T2 - Mendeleev Communications
AU - Shavelkina, Katherina S
AU - Bubenov, Sergei Sergeevich
AU - Popelensky, Vadim Mikhailovich
AU - Cherednichenko, Kirill Alekseevich
AU - Vinokurov, Alexander Alexandrovich
AU - Rybina, Valeriya V
AU - Dorofeev, Sergey Gennadievich
PY - 2026
DA - 2026/07/28
PB - Mendeleev Communications
SP - 617-619
IS - 5
VL - 36
ER -
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@article{2026_Shavelkina,
author = {Katherina S Shavelkina and Sergei Sergeevich Bubenov and Vadim Mikhailovich Popelensky and Kirill Alekseevich Cherednichenko and Alexander Alexandrovich Vinokurov and Valeriya V Rybina and Sergey Gennadievich Dorofeev},
title = {Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8051},
number = {5},
pages = {617--619},
doi = {10.71267/mencom.8051}
}
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Shavelkina, Katherina S., et al. “Raman studies of the reversible nanoscale Si–SiP transition in phosphorus vapor.” Mendeleev Communications, vol. 36, no. 5, Jul. 2026, pp. 617-619. https://mendcomm.colab.ws/publications/10.71267/mencom.8051.
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Keywords

nanocrystals
Raman spectroscopy
silicon
silicon phosphide
transmission electron microscopy

Abstract

Silicon nanocrystals were converted into orthorhombic SiP at higher phosphorus pressures than the bulk material due to the formation of a new surface. At the test temperatures of 780–840 °C, both forward and reverse reactions retained the nanoscale dimensions of particles as sintering was slow in the absence of a liquid phase.

Funders

Russian Science Foundation
24-73-10045

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