Home / Publications / Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties

Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties

, 
Vladimir Romanovich Belosludov 1, 2
Vladimir Romanovich Belosludov
,  , 
Vadim A Knyazkov 2, 3
Vadim A Knyazkov
,  ,  , 
Nina F Beizel 1, 2
Nina F Beizel
10.71267/mencom.7878
Published 2025-11-29
Communication , Volume 36, Issue 1, 104-106
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Bozhko Y. Yu. et al. Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 104-106.
GOST all authors (up to 50) Copy
Bozhko Y. Yu., Belosludov V. R., Matskevich N. I., Knyazkov V. A., Klimov B. A., Semerikova A. N., Beizel N. F. Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 104-106.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7878
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7878
TI - Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties
T2 - Mendeleev Communications
AU - Bozhko, Yulia Yu
AU - Belosludov, Vladimir Romanovich
AU - Matskevich, Nata Ivanovna
AU - Knyazkov, Vadim A
AU - Klimov, Bogdan A
AU - Semerikova, Anna Nikolaevna
AU - Beizel, Nina F
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 104-106
IS - 1
VL - 36
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Bozhko,
author = {Yulia Yu Bozhko and Vladimir Romanovich Belosludov and Nata Ivanovna Matskevich and Vadim A Knyazkov and Bogdan A Klimov and Anna Nikolaevna Semerikova and Nina F Beizel},
title = {Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7878},
number = {1},
pages = {104--106},
doi = {10.71267/mencom.7878}
}
MLA
Cite this
MLA Copy
Bozhko, Yulia Yu., et al. “Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 104-106. https://mendcomm.colab.ws/publications/10.71267/mencom.7878.
Views
8

Keywords

carbon dioxide hydrate
enthalpy
lithium chloride
modeling.
solution calorimetry
synthesis under pressure

Abstract

For the first time, carbon dioxide hydrate was synthesized from a 1% lithium chloride solution and CO2 gas under pressure; the decomposition enthalpy was measured by solution calorimetry. It was shown experimentally and computationally that addition of lithium chloride to water leads to a decrease in synthesis temperature. Lithium ions were partially incorporated into the structure of CO2 hydrate, and the remaining solution was enriched with lithium.

Funders

Russian Science Foundation
25-19-00816

References

1.
Lithium availability and future production outlooks
Vikström H., Davidsson S., Höök M.
Applied Energy, 2013
3.
Kutovaya I.V., Hizbullin A.A., Fedotov S.S., Shmatova O.I.
Mendeleev Communications, 2024
4.
Samarin A.S., Ivanova T.V., Nazarov E.E., Marshenya S.N., Luchinin N.D., Antipov E.V., Fedotov S.S.
Mendeleev Communications, 2024
7.
Lithium extraction by metal–organic frameworks
Han Z., Rushlow J., Yang Y., Huo J., Shi W., Zhou H.
Inorganic Chemistry Frontiers, 2024
8.
Buldashov I.A., Medvedev A.G., Mikhaylov A.A., Churakov A.V., Prikhodchenko P.V.
Mendeleev Communications, 2024
9.
Gryzlov D.Y., Kulova T.L., Nugmanova A.G., Skundin A.M., Kudryashova Y.O.
Mendeleev Communications, 2024
10.
Novikova S.A., Voropaeva D.Y., Li S.A., Kulova T.L., Skundin A.M., Stenina I.A., Yaroslavtsev A.B.
Mendeleev Communications, 2024
11.
Gas hydrates in sustainable chemistry
Hassanpouryouzband A., Joonaki E., Vasheghani Farahani M., Takeya S., Ruppel C., Yang J., English N.J., Schicks J.M., Edlmann K., Mehrabian H., Aman Z.M., Tohidi B.
Chemical Society Reviews, 2020
13.
Experimental and Computational insights into sustainable lithium recovery and freshwater production via CO2 Hydrate-Based desalination
Lim S.G., Moon D., Oh C.Y., Choi H.R., Sung C., Kim S.H., Ra K., Cha M., Yoon J.
Chemical Engineering Journal, 2025
14.
Experimental Methane Hydrate Dissociation Conditions in Aqueous Solutions of Lithium Salts
Windmeier C., Oellrich L.R.
Journal of Chemical & Engineering Data, 2014
16.
Transformation of hydrogen bond network during CO2 clathrate hydrate dissociation
Gets K., Belosludov V., Zhdanov R., Bozhko Y., Belosludov R., Subbotin O., Marasanov N., Kawazoe Y.
Applied Surface Science, 2020
17.
Molecular Dynamics Study of Clathrate-like Ordering of Water in Supersaturated Methane Solution at Low Pressure
Belosludov R.V., Gets K.V., Zhdanov R.K., Bozhko Y.Y., Belosludov V.R., Chen L., Kawazoe Y.
Molecules, 2023
18.
Effect of the THF molecules on the hydrate cavities formation with adding NaCL molecules into the modeling system
Bozhko Y.Y., Zhdanov R.K., Getz K.V., Belosludov V.R.
Journal of Physics: Conference Series, 2021
20.
Phase Equilibrium for Hydrofluorocarbon R134a Hydrate. Hydrate-Based Desalination of NaCl Salt Solution
Meleshkin A.V., Sagidullin A.K., Misyura S.Y., Morozov V.S., Marasanov N.V., Glezer V.V., Madygulov M.S., Mito M.T.
Journal of Engineering Thermophysics, 2024
21.
A Review of Gas Capture and Liquid Separation Technologies by CO2 Gas Hydrate
Misyura S., Strizhak P., Meleshkin A., Morozov V., Gaidukova O., Shlegel N., Shkola M.
Energies, 2023
22.
Matskevich N.I., Grigorieva V.D., Semerikova A.N., Shlegel V.N., Matskevich M.Y., Anyfrieva O.I.
Mendeleev Communications, 2023
23.
Matskevich N.I., Kochelakov D.V., Samoshkin D.A., Stankus S.V., Semerikova A.N., Rozhina M.Y., Anyfrieva O.I.
Mendeleev Communications, 2024
25.
The Enthalpy of Solution of SRM 1655 (KCl) in H2O.
Kilday M.V.
Journal of Research of the National Bureau of Standards, 1980
26.
An interlaboratory test for certification of potassium chloride as a certified reference material (CRM) for solution calorimetry
Günther C., Pfestorf R., Rother M., Seidel J., Zimmermann R., Wolf G., Schröder V.
Journal of Thermal Analysis and Calorimetry, 1988