Home / Publications / C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling

C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling

Margarita B. Timerkaeva 1
Margarita B. Timerkaeva
, 
Konstantin Aleksandrovich Kochetkov 1
Konstantin Aleksandrovich Kochetkov
, 
10.71267/mencom.7836
Published 2025-11-29
Communication , Volume 36, Issue 1, 41-43
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Timerkaeva M. B., Kochetkov K. A., Gorunova O. N. C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 41-43.
GOST all authors (up to 50) Copy
Timerkaeva M. B., Kochetkov K. A., Gorunova O. N. C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 41-43.
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TY - JOUR
DO - 10.71267/mencom.7836
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7836
TI - C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling
T2 - Mendeleev Communications
AU - Timerkaeva, Margarita B.
AU - Kochetkov, Konstantin Aleksandrovich
AU - Gorunova, Olga Nikolaevna
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 41-43
IS - 1
VL - 36
ER -
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@article{2025_Timerkaeva,
author = {Margarita B. Timerkaeva and Konstantin Aleksandrovich Kochetkov and Olga Nikolaevna Gorunova},
title = {C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7836},
number = {1},
pages = {41--43},
doi = {10.71267/mencom.7836}
}
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Timerkaeva, Margarita B., et al. “C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki-Miyaura cross-coupling.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 41-43. https://mendcomm.colab.ws/publications/10.71267/mencom.7836.

Keywords

aryl halides
biaryls.
binuclear C
N-palladacycle
palladium nanoparticles
phosphine-free catalysts
Suzuki�Miyaura cross-coupling

Abstract

Phosphine-free cyclopalladated binuclear complex based on N,N-dimethyl-N-(diphenylmethyl)amine shows high catalytic efficiency for the Suzuki-Miyaura reaction of aryl halides with arylboronic acids under mild conditions. The catalytic process for the coupling is proved by dynamic light scattering analysis to proceed on Pd0 nanoparticles. Palladium nanoparticles protected by tetrabutylammonium bromide and polyvinylpyrrolidone exhibit lower activities for the coupling reactions than those generated in situ without additives.

Funders

Ministry of Education and Science of the Russian Federation
075-00276-25-00

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