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Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition

Amir M. Al Mufti 1, 2
Amir M. Al Mufti
, 
Viktoria Алексеевна Ikonnikova 1
Viktoria Алексеевна Ikonnikova
, 
Alexander Yuryevich Smirnov 1, 3
Alexander Yuryevich Smirnov
, 
Pavel Nikolaevich Solyev 4
Pavel Nikolaevich Solyev
, 
Alexander Aleksandrovich Korlyukov 3, 5
Alexander Aleksandrovich Korlyukov
, 
Mohamad Nurul Azmi 6
Mohamad Nurul Azmi
, 
Mikhail S. Baranov 1, 3
Mikhail S. Baranov
, 
Andrey Andreevich Mikhaylov 1, 3
Andrey Andreevich Mikhaylov
10.71267/mencom.7781
Published 2025-07-17
Communication , Volume 35, Issue 5, 512-514
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Al Mufti A. M. et al. Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition // Mendeleev Communications. 2025. Vol. 35. No. 5. pp. 512-514.
GOST all authors (up to 50) Copy
Al Mufti A. M., Ikonnikova V. А., Smirnov A. Y., Solyev P. N., Korlyukov A. A., Azmi M. N., Baranov M. S., Mikhaylov A. A. Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition // Mendeleev Communications. 2025. Vol. 35. No. 5. pp. 512-514.
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TY - JOUR
DO - 10.71267/mencom.7781
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7781
TI - Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition
T2 - Mendeleev Communications
AU - Al Mufti, Amir M.
AU - Ikonnikova, Viktoria Алексеевна
AU - Smirnov, Alexander Yuryevich
AU - Solyev, Pavel Nikolaevich
AU - Korlyukov, Alexander Aleksandrovich
AU - Azmi, Mohamad Nurul
AU - Baranov, Mikhail S.
AU - Mikhaylov, Andrey Andreevich
PY - 2025
DA - 2025/07/17
PB - Mendeleev Communications
SP - 512-514
IS - 5
VL - 35
ER -
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@article{2025_Al Mufti,
author = {Amir M. Al Mufti and Viktoria Алексеевна Ikonnikova and Alexander Yuryevich Smirnov and Pavel Nikolaevich Solyev and Alexander Aleksandrovich Korlyukov and Mohamad Nurul Azmi and Mikhail S. Baranov and Andrey Andreevich Mikhaylov},
title = {Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7781},
number = {5},
pages = {512--514},
doi = {10.71267/mencom.7781}
}
MLA
Cite this
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Al Mufti, Amir M., et al. “Tracking the reactivity of arylideneimidazol-4-ones in the Diels-Alder cycloaddition.” Mendeleev Communications, vol. 35, no. 5, Jul. 2025, pp. 512-514. https://mendcomm.colab.ws/publications/10.71267/mencom.7781.
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Keywords

[4+2]-cycloaddition
catalysis
Diels–Alder reaction
imidazol-4-one.
spirocyclic compounds

Abstract

Previously unknown [4+2]-cycloaddition of 5-arylideneimidazol-4-ones with dienes leading to 1,3-diazaspiro[4.5]deca-1,7-dien-4-ones is proceeding under either Lewis acid catalysis or upon thermal initiation. Arylideneimidazol-4-ones with electron-donating groups display low reactivity, which could be overcome by introduction of trifluoromethyl group in the 2-position of imidazol-4-one.

References

[1]

Funders

Russian Science Foundation
23-73-10004

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