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A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones

Minggang Zhao 1
Minggang Zhao
, 
Fei Ma 1
Fei Ma
, 
Jian Xin Chen 1
Jian Xin Chen
1 Key Laboratory of Magnetic Molecules and Magnetic Information Materials, College of Chemistry and Materials Science, Shanxi Normal University, 030031 Taiyuan, P. R. China
10.71267/mencom.7707
Published 2025-05-21
Communication , Volume 35, Issue 4, 470-471
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Zhao M., Ma F., Chen J. X. A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 470-471.
GOST all authors (up to 50) Copy
Zhao M., Ma F., Chen J. X. A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones // Mendeleev Communications. 2025. Vol. 35. No. 4. pp. 470-471.
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TY - JOUR
DO - 10.71267/mencom.7707
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7707
TI - A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones
T2 - Mendeleev Communications
AU - Zhao, Minggang
AU - Ma, Fei
AU - Chen, Jian Xin
PY - 2025
DA - 2025/05/21
PB - Mendeleev Communications
SP - 470-471
IS - 4
VL - 35
ER -
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@article{2025_Zhao,
author = {Minggang Zhao and Fei Ma and Jian Xin Chen},
title = {A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7707},
number = {4},
pages = {470--471},
doi = {10.71267/mencom.7707}
}
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Zhao, Minggang, et al. “A practical carbamoylsilane-based synthesis of β-arylidene N-methoxymethyl α-siloxy carboxamides from α,β-enones.” Mendeleev Communications, vol. 35, no. 4, May. 2025, pp. 470-471. https://mendcomm.colab.ws/publications/10.71267/mencom.7707.

Keywords

aminocarbonylation
carbamoylsilanes
unsaturated ketones
β-arylidene α-siloxy carboxamides

Abstract

Using N-methoxymethyl-N-methylcarbamoylsilane as potent secondary amide source, the direct transformation of β-aryl-α,β-enones into the corresponding N,N-disubstituted β-arylidene α-siloxy carboxamides via the aminocarbonylation reaction is described. The reactions provide good yields of the products under simple and catalyst-free conditions.

Funders

Engineering of Shanxi Province
0713