Home / Publications / Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers

Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
,  , 
10.71267/mencom.7634
Published 2025-02-18
Communication , Volume 35, Issue 2, 130-132
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Tamm N. B., Markov V. Y., Troyanov S. I. Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 130-132.
GOST all authors (up to 50) Copy
Tamm N. B., Markov V. Y., Troyanov S. I. Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 130-132.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7634
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7634
TI - Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Markov, Vitaliy Yuryevich
AU - Troyanov, Sergey Igorevich
PY - 2025
DA - 2025/02/18
PB - Mendeleev Communications
SP - 130-132
IS - 2
VL - 35
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Tamm,
author = {Nadezhda Borisovna Tamm and Vitaliy Yuryevich Markov and Sergey Igorevich Troyanov},
title = {Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7634},
number = {2},
pages = {130--132},
doi = {10.71267/mencom.7634}
}
MLA
Cite this
MLA Copy
Tamm, Nadezhda Borisovna, et al. “Synthesis, HPLC isolation and structural characterization of three new C60(CF3)18 isomers.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 130-132. https://mendcomm.colab.ws/publications/10.71267/mencom.7634.

Keywords

fullerene C60
HPLC separation
structure elucidation.
synchrotron radiation
trifluoromethylation

Abstract

Three new C60(CF3)18 isomers have been synthesized by high-temperature trifluoromethylation of [60]fullerene with gaseous CF3I, isolated by HPLC, and structurally characterized by single crystal X-ray diffraction using synchrotron radiation.

Funders

Ministry of Education and Science of the Russian Federation
21031300039-1

References

.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996
.
Perfluoroalkylfullerenes
Boltalina O.V., Popov A.A., Kuvychko I.V., Shustova N.B., Strauss S.H.
Chemical Reviews, 2015
.
Electrochemical, spectroscopic, and DFT study of C60(CF3)n frontier orbitals (n = 2-18): the link between double bonds in pentagons and reduction potentials.
Popov A.A., Kareev I.E., Shustova N.B., Stukalin E.B., Lebedkin S.F., Seppelt K., Strauss S.H., Boltalina O.V., Dunsch L.
Journal of the American Chemical Society, 2007
.
Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern:  C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6
Kareev I.E., Shustova N.B., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2006
.
X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 °C
Kareev I.E., Shustova N.B., Peryshkov D.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Boltalina O.V., Strauss S.H.
Chemical Communications, 2007
.
Synthesis, Spectroscopic and Electrochemical Characterization, and DFT Study of Seventeen C70(CF3)nDerivatives (n=2, 4, 6, 8, 10, 12)
Popov A., Kareev I., Shustova N., Lebedkin S., Strauss S., Boltalina O., Dunsch L.
Chemistry - A European Journal, 2007
.
Tamm N.B., Brotsman V.A., Troyanov S.I.
Mendeleev Communications, 2023
.
Structures and structure-related electronic properties of new C60(CF3)10 isomers
Bukovsky E.V., Larson B.W., Clikeman T.T., Chen Y., Popov A.A., Boltalina O.V., Strauss S.H.
Journal of Fluorine Chemistry, 2016
.
Higher trifluoromethylated derivatives of C60, C60(CF3)16 and C60(CF3)18
Troyanov S.I., Goryunkov A.A., Dorozhkin E.I., Ignat’eva D.V., Tamm N.B., Avdoshenko S.M., Ioffe I.N., Markov V.Y., Sidorov L.N., Scheurel K., Kemnitz E.
Journal of Fluorine Chemistry, 2007
.
[60]- and [70]Fullerenes are trifluoromethylated across 5:6-bonds
Darwish A.D., Avent A.G., Abdul-Sada A.K., Taylor R.
Chemical Communications, 2003
.
Trifluoromethylation of Fullerenes: Kinetic and Thermodynamic Control
Ignat’eva D.V., Goryunkov A.A., Ioffe I.N., Sidorov L.N.
Journal of Physical Chemistry A, 2013
.
1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene
Shustova N.B., Anderson O.P., Boltalina O.V., Strauss S.H., Kareev I.E.
Acta Crystallographica Section E Structure Reports Online, 2007
.
Isolation and Structural Characterization of the Most Stable, Highly Symmetric Isomer of C60(CF3)18
Samokhvalova N.A., Khavrel P.A., Markov V.Y., Samokhvalov P.S., Goruynkov A.A., Kemnitz E., Sidorov L.N., Troyanov S.I.
European Journal of Organic Chemistry, 2009
.
Numbering of Fullerenes (IUPAC Recommendations 2004)
Cozzi F., Powell W.H., Thilgen C.
Pure and Applied Chemistry, 2005
.
Tamm N.B., Troyanov S.I.
Mendeleev Communications, 2025