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Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
10.1070/MC1994v004n01ABEH000322
Published 1994-02-28
Communication , Volume 4, Issue 1, 4-5
6
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Vasil'ev A. A., Serebryakov E. P. Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 4-5.
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Vasil'ev A. A., Serebryakov E. P. Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids // Mendeleev Communications. 1994. Vol. 4. No. 1. pp. 4-5.
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TY - JOUR
DO - 10.1070/MC1994v004n01ABEH000322
UR - https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000322
TI - Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Serebryakov, Edward Prokof'evich
PY - 1994
DA - 1994/02/28
PB - Mendeleev Communications
SP - 4-5
IS - 1
VL - 4
ER -
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@article{1994_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Edward Prokof'evich Serebryakov},
title = {Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids},
journal = {Mendeleev Communications},
year = {1994},
volume = {4},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000322},
number = {1},
pages = {4--5},
doi = {10.1070/MC1994v004n01ABEH000322}
}
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Vasil'ev, Andrei Alexandrovich, and Edward Prokof'evich Serebryakov. “Catalytic Hydrogenation/Enzymic Hydrolysis as a Route from Alkyl Alka-2,4-dienoates to (Z)-Alk-3-enoic Acids.” Mendeleev Communications, vol. 4, no. 1, Feb. 1994, pp. 4-5. https://mendcomm.colab.ws/publications/10.1070/MC1994v004n01ABEH000322.

Abstract

(Z)-Alk-3-enoic acids of no less than 94% geometrical purity have been obtained from the respective alkyl alka-2,4-dienoates after hydrogenation over chromium hexacarbonyl followed by hydrolysis of the resulting products using porcine pancreatic lipase or KOH in H2O/MeOH.

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