Home / Publications / An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis

An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis

Felix Samuilovich Sirovskii 1
Felix Samuilovich Sirovskii
, 
Elena Alekseevna Bobrova 1
Elena Alekseevna Bobrova
1 SIMS Co., Ltd., Moscow, Russian Federation
10.1070/MC1993v003n06ABEH000312
Published 1993-12-31
Communication , Volume 3, Issue 6, 243-244
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Sirovskii F. S., Bobrova E. A. An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 243-244.
GOST all authors (up to 50) Copy
Sirovskii F. S., Bobrova E. A. An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis // Mendeleev Communications. 1993. Vol. 3. No. 6. pp. 243-244.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1993v003n06ABEH000312
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000312
TI - An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis
T2 - Mendeleev Communications
AU - Sirovskii, Felix Samuilovich
AU - Bobrova, Elena Alekseevna
PY - 1993
DA - 1993/12/31
PB - Mendeleev Communications
SP - 243-244
IS - 6
VL - 3
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Sirovskii,
author = {Felix Samuilovich Sirovskii and Elena Alekseevna Bobrova},
title = {An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000312},
number = {6},
pages = {243--244},
doi = {10.1070/MC1993v003n06ABEH000312}
}
MLA
Cite this
MLA Copy
Sirovskii, Felix Samuilovich, and Elena Alekseevna Bobrova. “An Unusual Selectivity Change in the Acetylation of 1,8-Dihydroxy-3,7-dimethyl-9- (2’,6’ 6’-trimethylcyclohexen-1’-yl)nona-2,4,6-triene under Phase-transfer Catalysis.” Mendeleev Communications, vol. 3, no. 6, Dec. 1993, pp. 243-244. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n06ABEH000312.

Abstract

During acetylation of an intermediate in vitamin A synthesis under phase-transfer catalysis in the solid-liquid system, only monosubstitution occurs in contrast to acetylation in the homogeneous system.

References

1.
10.1070/MC1993v003n06ABEH000312_bib1
Schnaidman
Proizvodstvo vitaminov (Manufacture of vitamins), 1973
2.
10.1070/MC1993v003n06ABEH000312_bib2
Dehmlow
Phase Transfer Catalysis, 1993