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Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η⁶-Arenetricarbonylchromium Complexes

Valery Nikolaevich Kalinin ¹

Valery Nikolaevich Kalinin

Ilya Aleksandrovich Cherepanov ¹

Ilya Aleksandrovich Cherepanov

Sergey Konstantinovich Moiseev ¹

Sergey Konstantinovich Moiseev

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1070/MC1992v002n03ABEH000161

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Published 1992-09-30

Communication , Volume 2, Issue 3, 113-114

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Kalinin V. N., Cherepanov I. A., Moiseev S. K. Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η6-Arenetricarbonylchromium Complexes // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 113-114.

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TY - JOUR

DO - 10.1070/MC1992v002n03ABEH000161

UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000161

TI - Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η6-Arenetricarbonylchromium Complexes

T2 - Mendeleev Communications

AU - Kalinin, Valery Nikolaevich

AU - Cherepanov, Ilya Aleksandrovich

AU - Moiseev, Sergey Konstantinovich

PY - 1992

DA - 1992/09/30

PB - Mendeleev Communications

SP - 113-114

IS - 3

VL - 2

ER -

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@article{1992_Kalinin,

author = {Valery Nikolaevich Kalinin and Ilya Aleksandrovich Cherepanov and Sergey Konstantinovich Moiseev},

title = {Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η6-Arenetricarbonylchromium Complexes},

journal = {Mendeleev Communications},

year = {1992},

volume = {2},

publisher = {Mendeleev Communications},

month = {Sep},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000161},

number = {3},

pages = {113--114},

doi = {10.1070/MC1992v002n03ABEH000161}

}

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Kalinin, Valery Nikolaevich, et al. “Synthesis of 2-Arylcarboxylic Acids and C-Norbenzomorphans via η6-Arenetricarbonylchromium Complexes.” Mendeleev Communications, vol. 2, no. 3, Sep. 1992, pp. 113-114. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000161.

Abstract

A method for the regioselective carboxylation of (η⁶-alkylarene)tricarbonylchromium complexes at the benzylic position has been developed via the reaction of the corresponding lithium derivatives with carbon dioxide in tetrahydrofuran; a method for the preparation of 5-acetoxy-3-benzyl-1,4-methano-2,3-4,5-tetrahydro-1H-3-benzazepine from 1-tetralol is described.