Home / Publications / CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide

CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide

Yan Vladislavovich Demyanov 1
Yan Vladislavovich Demyanov
, 
Irina Yur'evna Bagryanskaya 2
Irina Yur'evna Bagryanskaya
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
1 A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
10.1016/j.mencom.2024.10.014
Published 2024-10-22
Communication , Volume 34, Issue 6, 812-814
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Demyanov Y. V., Bagryanskaya I. Y., Artem’ev A. V. CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 812-814.
GOST all authors (up to 50) Copy
Demyanov Y. V., Bagryanskaya I. Y., Artem’ev A. V. CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 812-814.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.014
TI - CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide
T2 - Mendeleev Communications
AU - Demyanov, Yan Vladislavovich
AU - Bagryanskaya, Irina Yur'evna
AU - Artem’ev, Alexandr Viktorovich
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 812-814
IS - 6
VL - 34
ER -
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@article{2024_Demyanov,
author = {Yan Vladislavovich Demyanov and Irina Yur'evna Bagryanskaya and Alexandr Viktorovich Artem’ev},
title = {CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.014},
number = {6},
pages = {812--814},
doi = {10.1016/j.mencom.2024.10.014}
}
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Demyanov, Yan Vladislavovich, et al. “CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 812-814. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.014.

Keywords

copper(I) and silver(I) complexes
crystal structure.
photoluminescence
tris(6-methyl-2-pyridyl)phosphine oxide

Abstract

The interaction of tris(6-methyl-2-pyridyl)phosphine oxide (L) with equimolar amounts of [Cu(MeCN)4]PF6 or AgClO4 in acetonitrile produces scorpionate-like complexes [M(L)(MeCN)]X (M = Cu and Ag; X = PF6- and ClO4-). At ambient temperature, these compounds exhibit orange (λmax = 608 nm) or turquoise (λmax = 490 nm) photo-luminescence with a quantum yield up to 16% and lifetimes of microsecond order.

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