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Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines

, 
Andrey Vyacheslavovich Rumyantsev 1, 2
Andrey Vyacheslavovich Rumyantsev
,  , 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
, 
Pavel Alexandrovich Zhizhko 1
Pavel Alexandrovich Zhizhko
, 
Dmitry Nikolaevich Zarubin 1
Dmitry Nikolaevich Zarubin
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.06.028
Published 2024-06-19
Communication , Volume 34, Issue 4, 555-557
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Bushkov N. S. et al. Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 555-557.
GOST all authors (up to 50) Copy
Bushkov N. S., Rumyantsev A. V., Zhizhin A. A., Godovikov I. A., Zhizhko P. A., Zarubin D. N. Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 555-557.
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TY - JOUR
DO - 10.1016/j.mencom.2024.06.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.028
TI - Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines
T2 - Mendeleev Communications
AU - Bushkov, Nikolai Sergeyevich
AU - Rumyantsev, Andrey Vyacheslavovich
AU - Zhizhin, Anton Andreevich
AU - Godovikov, Ivan Alexandrovich
AU - Zhizhko, Pavel Alexandrovich
AU - Zarubin, Dmitry Nikolaevich
PY - 2024
DA - 2024/06/19
PB - Mendeleev Communications
SP - 555-557
IS - 4
VL - 34
ER -
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@article{2024_Bushkov,
author = {Nikolai Sergeyevich Bushkov and Andrey Vyacheslavovich Rumyantsev and Anton Andreevich Zhizhin and Ivan Alexandrovich Godovikov and Pavel Alexandrovich Zhizhko and Dmitry Nikolaevich Zarubin},
title = {Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.028},
number = {4},
pages = {555--557},
doi = {10.1016/j.mencom.2024.06.028}
}
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Bushkov, Nikolai Sergeyevich, et al. “Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 555-557. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.028.

Keywords

heterometathesis
imides
imido complexes
metathesis
N-sulfinylamine
sulfurdiimine.
titanium complexes

Abstract

Well-defined silica-supported Ti imido complex (≡SiO)Ti(=NBut)(Me2Pyr)(Py)2 (Me2Pyr = 2,5-dimethyl- pyrrolyl) catalyzes condensation of N-sulfinylanilines into sulfurdiimines via the oxo/imido heterometathesis providing a convenient synthetic route to functionalized sulfurdiimines.

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