Home / Publications / Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene

Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene

1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.04.031
Published 2024-04-22
Communication , Volume 34, Issue 3, 409-410
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Troyanov S. I. Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 409-410.
GOST all authors (up to 50) Copy
Troyanov S. I. Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 409-410.
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TY - JOUR
DO - 10.1016/j.mencom.2024.04.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.031
TI - Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene
T2 - Mendeleev Communications
AU - Troyanov, Sergey Igorevich
PY - 2024
DA - 2024/04/22
PB - Mendeleev Communications
SP - 409-410
IS - 3
VL - 34
ER -
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@article{2024_Troyanov,
author = {Sergey Igorevich Troyanov},
title = {Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.031},
number = {3},
pages = {409--410},
doi = {10.1016/j.mencom.2024.04.031}
}
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Troyanov, Sergey Igorevich. “Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene.” Mendeleev Communications, vol. 34, no. 3, Apr. 2024, pp. 409-410. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.031.

Keywords

C84
chlorination
higher fullerenes
IPR isomers
structure elucidation.

Abstract

Chlorofullerene D2d-C84(23)Cl24 was prepared by chlorination of D2d-C84(23) with VCl4 or SbCl5 at 320-350 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the addition pattern of 24 Cl atoms stabilized by the formation of isolated C=C bonds and benzenoid rings on the carbon cage.

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