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Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]

Daria V Sedlova 1, 2
Daria V Sedlova
, 
Elena Sergeevna Osipova 1
Elena Sergeevna Osipova
, 
Evgenii Ivanovich Gutsul 1
Evgenii Ivanovich Gutsul
, 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
,  ,  , 
Natalia Viktorovna Belkova 1
Natalia Viktorovna Belkova
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region, Russian Federation
10.1016/j.mencom.2024.02.010
Published 2024-02-19
Communication , Volume 34, Issue 2, 192-194
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Sedlova D. V. et al. Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)] // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 192-194.
GOST all authors (up to 50) Copy
Sedlova D. V., Osipova E. S., Gutsul E. I., Godovikov I. A., Filippov O. A., Shubina E. S., Belkova N. V. Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)] // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 192-194.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.010
TI - Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]
T2 - Mendeleev Communications
AU - Sedlova, Daria V
AU - Osipova, Elena Sergeevna
AU - Gutsul, Evgenii Ivanovich
AU - Godovikov, Ivan Alexandrovich
AU - Filippov, Oleg Andreevich
AU - Shubina, Elena Solomonovna
AU - Belkova, Natalia Viktorovna
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 192-194
IS - 2
VL - 34
ER -
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@article{2024_Sedlova,
author = {Daria V Sedlova and Elena Sergeevna Osipova and Evgenii Ivanovich Gutsul and Ivan Alexandrovich Godovikov and Oleg Andreevich Filippov and Elena Solomonovna Shubina and Natalia Viktorovna Belkova},
title = {Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.010},
number = {2},
pages = {192--194},
doi = {10.1016/j.mencom.2024.02.010}
}
MLA
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Sedlova, Daria V., et al. “Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)].” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 192-194. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.010.

Keywords

bimetallic catalysis
carbon dioxide
hydrosilylation
IR spectroscopy.
pincer complexes
Reaction mechanism

Abstract

The interaction of bimetallic (t-BuPCP)Pd···(OC)M(CO)2 Cp (M = Mo, W) complexes with PhSiH3 leads to an efficient heterolytic splitting of Si-H bond that is a primary step in catalytic hydrosilylation of CO2. The reaction can be stopped at the formate level in the presence of the above complexes while proceeds further when catalyzed by (t-BuPCP)PdH.

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