Home / Publications / Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]−

Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]−

Kirill Igorevich Tugashov 1
Kirill Igorevich Tugashov
, 
Maxim Vladimirovich Andreev 1
Maxim Vladimirovich Andreev
, 
Mikhail Alekseevich Frolov 1
Mikhail Alekseevich Frolov
, 
Vyacheslav Sergeevich Bogdanov 1
Vyacheslav Sergeevich Bogdanov
, 
Alexander Fedorovich Smol'yakov 1, 2
Alexander Fedorovich Smol'yakov
, 
Fedor Mikhailovich Dolgushin 2, 3
Fedor Mikhailovich Dolgushin
, 
Vladimir Vasil'evich Burlakov 1
Vladimir Vasil'evich Burlakov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
10.1016/j.mencom.2024.02.009
Published 2024-02-19
Communication , Volume 34, Issue 2, 188-191
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Tugashov K. I. et al. Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]− // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 188-191.
GOST all authors (up to 50) Copy
Tugashov K. I., Andreev M. V., Frolov M. A., Bogdanov V. S., Smol'yakov A. F., Dolgushin F. M., Burlakov V. V. Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]− // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 188-191.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2024.02.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.009
TI - Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]−
T2 - Mendeleev Communications
AU - Tugashov, Kirill Igorevich
AU - Andreev, Maxim Vladimirovich
AU - Frolov, Mikhail Alekseevich
AU - Bogdanov, Vyacheslav Sergeevich
AU - Smol'yakov, Alexander Fedorovich
AU - Dolgushin, Fedor Mikhailovich
AU - Burlakov, Vladimir Vasil'evich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 188-191
IS - 2
VL - 34
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Tugashov,
author = {Kirill Igorevich Tugashov and Maxim Vladimirovich Andreev and Mikhail Alekseevich Frolov and Vyacheslav Sergeevich Bogdanov and Alexander Fedorovich Smol'yakov and Fedor Mikhailovich Dolgushin and Vladimir Vasil'evich Burlakov},
title = {Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]−},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.009},
number = {2},
pages = {188--191},
doi = {10.1016/j.mencom.2024.02.009}
}
MLA
Cite this
MLA Copy
Tugashov, Kirill Igorevich, et al. “Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]−.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 188-191. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.009.

Keywords

anticrown compounds
bromide.
complexation
hafnium
mercury
metallacyclocumulene

Abstract

The first bromide complex of the tetramercury anticrown, [(o,o’-C6F4C6F4Hg)4Br]− (PyH)+, was synthesized by the reaction of alkenyl bromide complex of hafnocene Cp2Hf(Br)-C(But)=C(H)-C≡CBut with cyclic tetrameric perfluoro-o,o’-biphenylenemercury (o,o’-C6F4C6F4Hg)4. The structures of the obtained complex and initial alkenyl bromide complex were studied by the X-ray diffraction analysis.

References

.
The van der Waals radius of mercury
Canty A.J., Deacon G.B.
Inorganica Chimica Acta, 1980
.
Synthesis and Isolation of Di-n-butylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New Hafnacycles
Burlakov V.V., Beweries T., Bogdanov V.S., Arndt P., Baumann W., Petrovskii P.V., Spannenberg A., Lyssenko K.A., Shur V.B., Rosenthal U.
Organometallics, 2009
.
Brintzinger H.H., Fischer D., Mülhaupt R., Rieger B., Waymouth R.M.
1995
.
Octahedral coordination of halide ions (I-, Br-, Cl-) sandwich bonded with tridentate mercuracarborand-3 receptors.
Lee H., Knobler C.B., Hawthorne M.F.
Journal of the American Chemical Society, 2001
.
First structurally characterized five-membered hafnacyclocumulene Cp2Hf(η4-ButC4But)
Burlakov V.V., Bogdanov V.S., Lyssenko K.A., Petrovskii P.V., Beweries T., Arndt P., Rosenthal U., Shura V.B.
Russian Chemical Bulletin, 2008
.
Andreev M.V., Bogdanov V.S., Frolov M.A., Nurzhanova E.R., Smol'yakov A.F., Burlakov V.V.
Mendeleev Communications, 2023