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Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8

Sofia Vadimovna Gracheva 1
Sofia Vadimovna Gracheva
, 
Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
Maria Petrovna Kosaya 1
Maria Petrovna Kosaya
, 
Alexey Vladimirovich Rybalchenko 1
Alexey Vladimirovich Rybalchenko
, 
Nikita M Belov 1
Nikita M Belov
, 
Natalya Sergeevna Lukonina 1
Natalya Sergeevna Lukonina
, 
Alexey Anatol'evich Goryunkov 1
Alexey Anatol'evich Goryunkov
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.02.005
Published 2024-02-19
Communication , Volume 34, Issue 2, 174-177
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Gracheva S. V. et al. Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8 // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 174-177.
GOST all authors (up to 50) Copy
Gracheva S. V., Tamm N. B., Kosaya M. P., Rybalchenko A. V., Belov N. M., Lukonina N. S., Goryunkov A. A. Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8 // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 174-177.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.005
TI - Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8
T2 - Mendeleev Communications
AU - Gracheva, Sofia Vadimovna
AU - Tamm, Nadezhda Borisovna
AU - Kosaya, Maria Petrovna
AU - Rybalchenko, Alexey Vladimirovich
AU - Belov, Nikita M
AU - Lukonina, Natalya Sergeevna
AU - Goryunkov, Alexey Anatol'evich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 174-177
IS - 2
VL - 34
ER -
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@article{2024_Gracheva,
author = {Sofia Vadimovna Gracheva and Nadezhda Borisovna Tamm and Maria Petrovna Kosaya and Alexey Vladimirovich Rybalchenko and Nikita M Belov and Natalya Sergeevna Lukonina and Alexey Anatol'evich Goryunkov},
title = {Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.005},
number = {2},
pages = {174--177},
doi = {10.1016/j.mencom.2024.02.005}
}
MLA
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Gracheva, Sofia Vadimovna, et al. “Synthesis, optical and electrochemical properties of regioisomeric methanofullerene derivatives of Cs-C70(CF3)8.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 174-177. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.005.

Keywords

addition pattern
cyclic voltammetry.
fluorescence
methanofullerene
trifluoromethylated fullerene

Abstract

The Bamford-Stevens reaction with Cs-C70(CF3)8 provides four regioisomeric cyclopropanated and at least one bis- cyclopropanated polyfunctional derivatives C70(CF3)8DPMn, n = 1, 2 [DPM = C(p-MeOC6H4)2]. A strong influence of the addition patterns on fluorescence and electrochemical properties is demonstrated for three spectrally identified monoadducts C70(CF3)8DPM.

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