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Oligomers based on cyanoacrylic acid esters

Valery Alexandrovich Dyatlov 1
Valery Alexandrovich Dyatlov
, 
Victoria G Kharitonova 2
Victoria G Kharitonova
, 
Daria Vladimirovna Kupriyanova 2
Daria Vladimirovna Kupriyanova
, 
Efrem Georgievich Krivoborodov 1
Efrem Georgievich Krivoborodov
, 
Igor Alekseevich Derevnin 1
Igor Alekseevich Derevnin
, 
Alexey Ivanovich Kovalev 2
Alexey Ivanovich Kovalev
, 
Irina Anatol'evna Khotina 2
Irina Anatol'evna Khotina
1 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
2 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.06.040
Published 2023-06-13
Communication , Volume 33, Issue 4, 565-567
2
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Dyatlov V. A. et al. Oligomers based on cyanoacrylic acid esters // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 565-567.
GOST all authors (up to 50) Copy
Dyatlov V. A., Kharitonova V. G., Kupriyanova D. V., Krivoborodov E. G., Derevnin I. A., Kovalev A. I., Khotina I. A. Oligomers based on cyanoacrylic acid esters // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 565-567.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.040
TI - Oligomers based on cyanoacrylic acid esters
T2 - Mendeleev Communications
AU - Dyatlov, Valery Alexandrovich
AU - Kharitonova, Victoria G
AU - Kupriyanova, Daria Vladimirovna
AU - Krivoborodov, Efrem Georgievich
AU - Derevnin, Igor Alekseevich
AU - Kovalev, Alexey Ivanovich
AU - Khotina, Irina Anatol'evna
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 565-567
IS - 4
VL - 33
ER -
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@article{2023_Dyatlov,
author = {Valery Alexandrovich Dyatlov and Victoria G Kharitonova and Daria Vladimirovna Kupriyanova and Efrem Georgievich Krivoborodov and Igor Alekseevich Derevnin and Alexey Ivanovich Kovalev and Irina Anatol'evna Khotina},
title = {Oligomers based on cyanoacrylic acid esters},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.040},
number = {4},
pages = {565--567},
doi = {10.1016/j.mencom.2023.06.040}
}
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Dyatlov, Valery Alexandrovich, et al. “Oligomers based on cyanoacrylic acid esters.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 565-567. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.040.

Keywords

dynamic light scattering.
ethyl 2-cyanoacrylate
fatty alcohols
MALDI-TOF mass-spectrometry
nanocapsules
oligomers

Abstract

Ethyl 3-alkoxy-2-cyanopropanoates were prepared by the reaction of ethyl 2-cyanoacrylate with the corresponding linear alkanols C6-C12 in acidic medium. Their treatment with water as a weak nucleophile resulted in elimination of the alkanol and the formation of oligocyanoacrylate terminated with the alkoxy group. The oligomers were studied by NMR spectroscopy, IR spectroscopy, MALDI-TOF mass-spectrometry and dynamic light scattering.

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