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Wolmershauser radicals: Chemistry and materials science

Alexander Andreevich Buravlev 1, 2
Alexander Andreevich Buravlev
Alexander Yur'evich Makarov 1
Alexander Yur'evich Makarov
Oleg Alexeevich Rakitin 3
Oleg Alexeevich Rakitin
Andrey Viktorovich Zibarev 1
Andrey Viktorovich Zibarev
Published 2023-06-13
CommunicationVolume 33, Issue 4, 439-447
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Buravlev A. A. et al. Wolmershauser radicals: Chemistry and materials science // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 439-447.
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Buravlev A. A., Makarov A. Y., Rakitin O. A., Zibarev A. V. Wolmershauser radicals: Chemistry and materials science // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 439-447.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.001
TI - Wolmershauser radicals: Chemistry and materials science
T2 - Mendeleev Communications
AU - Buravlev, Alexander Andreevich
AU - Makarov, Alexander Yur'evich
AU - Rakitin, Oleg Alexeevich
AU - Zibarev, Andrey Viktorovich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 439-447
IS - 4
VL - 33
ER -
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@article{2023_Buravlev,
author = {Alexander Andreevich Buravlev and Alexander Yur'evich Makarov and Oleg Alexeevich Rakitin and Andrey Viktorovich Zibarev},
title = {Wolmershauser radicals: Chemistry and materials science},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.001},
number = {4},
pages = {439--447},
doi = {10.1016/j.mencom.2023.06.001}
}
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Cite this
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Buravlev, Alexander Andreevich, et al. “Wolmershauser radicals: Chemistry and materials science.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 439-447. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.001.

Keywords

1
2-benzodithiazolyls
3
chalcogen–nitrogen π-heterocycles
conducting molecular materials
magnetic molecular materials
reactivity
structure
synthesis
Wolmershäuser radicals.

Abstract

Chemistry and materials science of stable 1,3,2-benzodi-thiazolyls (Wolmershauser radicals) are discussed. These easily-accessible chromogenic and redox-active compounds are promising building blocks of conductive and magnetic molecular materials including spin-crossover materials. Their comparison with 1,2,3-isomers (Herz radicals), also involved in contemporary materials science, is given.

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