Home / Publications / New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells

New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells

Sergei Alexandrovich Kuklin 1, 2
Sergei Alexandrovich Kuklin
, 
Sergey Vladimirovich Safronov 1
Sergey Vladimirovich Safronov
, 
Ekaterina Aleksandrovna Khakina 1
Ekaterina Aleksandrovna Khakina
, 
Anastasiya Georgievna Buyanovskaya 1
Anastasiya Georgievna Buyanovskaya
, 
Lyubov' Anatol'evna Frolova 2
Lyubov' Anatol'evna Frolova
, 
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
10.1016/j.mencom.2023.04.005
Published 2023-04-13
Communication , Volume 33, Issue 3, 314-317
5
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kuklin S. A. et al. New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 314-317.
GOST all authors (up to 50) Copy
Kuklin S. A., Safronov S. V., Khakina E. A., Buyanovskaya A. G., Frolova L. A., Troshin P. A. New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 314-317.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2023.04.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.005
TI - New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells
T2 - Mendeleev Communications
AU - Kuklin, Sergei Alexandrovich
AU - Safronov, Sergey Vladimirovich
AU - Khakina, Ekaterina Aleksandrovna
AU - Buyanovskaya, Anastasiya Georgievna
AU - Frolova, Lyubov' Anatol'evna
AU - Troshin, Pavel Anatol'evich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 314-317
IS - 3
VL - 33
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Kuklin,
author = {Sergei Alexandrovich Kuklin and Sergey Vladimirovich Safronov and Ekaterina Aleksandrovna Khakina and Anastasiya Georgievna Buyanovskaya and Lyubov' Anatol'evna Frolova and Pavel Anatol'evich Troshin},
title = {New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.005},
number = {3},
pages = {314--317},
doi = {10.1016/j.mencom.2023.04.005}
}
MLA
Cite this
MLA Copy
Kuklin, Sergei Alexandrovich, et al. “New perylene diimide electron acceptors for organic electronics: Synthesis, optoelectronic properties and performance in perovskite solar cells.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 314-317. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.005.

Keywords

2-b:4
2'-g]isoindole
3-b':6
3-e:3'
7-c'']trithiophene
anthra[1
dithieno[2
electron transport materials.
PDI derivatives
perovskite solar cells
perylene diimide
small molecules
Sonogashira coupling
Stille coupling

Abstract

Two new non-fullerene acceptors based on perylene diimide with acetylenic bridges were designed and synthesized employing Stille and Sonogashira coupling reactions as the key steps. Their optical and electronic properties were explored by UV-VIS spectroscopy and cyclic voltammetry, and energies of frontier molecular orbitals were estimated. Their preliminary studies in perovskite solar cells as electron transport materials showed the best power conversion efficiency for photocells of 14.18% value.

References

.
Strategies of modifying spiro-OMeTAD materials for perovskite solar cells: a review
Ren G., Han W., Deng Y., Wu W., Li Z., Guo J., Bao H., Liu C., Guo W.
Journal of Materials Chemistry A, 2021
.
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Kojima A., Teshima K., Shirai Y., Miyasaka T.
Journal of the American Chemical Society, 2009
.
Organic solar cells based on non-fullerene acceptors
Hou J., Inganäs O., Friend R.H., Gao F.
Nature Materials, 2018
.
New Donor-Acceptor polymers with a wide absorption range for photovoltaic applications
Keshtov M.L., Kuklin S.A., Konstantinov I.O., Ostapov I.E., Xie Z., Koukaras E.N., Suthar R., Sharma G.D.
Solar Energy, 2020
.
Tuning orbital energetics in arylene diimide semiconductors. materials design for ambient stability of n-type charge transport.
Jones B.A., Facchetti A., Wasielewski M.R., Marks T.J.
Journal of the American Chemical Society, 2007
.
CsF-Mediated in Situ Desilylation of TMS-Alkynes for Sonogashira Reaction
Capani J.S., Cochran J.E., Liang J.(.
Journal of Organic Chemistry, 2019
.
Perylene Diimide-Based Oligomers and Polymers for Organic Optoelectronics
Cheng P., Zhao X., Zhan X.
Accounts of Materials Research, 2022
.
Multiple Cases of Efficient Nonfullerene Ternary Organic Solar Cells Enabled by an Effective Morphology Control Method
Jiang K., Zhang G., Yang G., Zhang J., Li Z., Ma T., Hu H., Ma W., Ade H., Yan H.
Advanced Energy Materials, 2017
.
High performance nonvolatile organic field‐effect transistor memory devices based on pyrene diimide derivative
Wang W.V., Zhang Y., Li X., Chen Z., Wu Z., Zhang L., Lin Z., Zhang H.
InfoMat, 2021
.
A perylene diimide-based electron transport layer enabling efficient inverted perovskite solar cells
Jiang K., Wu F., Yu H., Yao Y., Zhang G., Zhu L., Yan H.
Journal of Materials Chemistry A, 2018
.
Pyrene-fused PDI based ternary solar cells: high power conversion efficiency over 10%, and improved device thermal stability
Gong Y., Chang K., Chen C., Han M., Zhan X., Min J., Jiao X., Li Q., Li Z.
Materials Chemistry Frontiers, 2019
.
Solution-processable perylene diimide-based electron transport materials as non-fullerene alternatives for inverted perovskite solar cells
Perez G.S., Dasgupta S., Żuraw W., Pineda R.F., Wojciechowski K., Jagadamma L.K., Samuel I., Robertson N.
Journal of Materials Chemistry A, 2022
.
A perylene diimide dimer-based electron transporting material with an A–D–A structure for efficient inverted perovskite solar cells
Fan Y., Wu F., Liu F., Han M., Chang K., Zhu L., Li Q., Li Z.
Journal of Materials Chemistry C, 2022
.
Kabanova V.A., Gribkova O.L., Tameev A.R., Nekrasov A.A.
Mendeleev Communications, 2021