Home / Publications / Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques

Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques

Nikita Andreevich Slesarenko 1
Nikita Andreevich Slesarenko
, 
Alexander Vladimirovich Chernyak 1, 2
Alexander Vladimirovich Chernyak
,  , 
Victor Petrovich Tarasov 1
Victor Petrovich Tarasov
, 
Vitaly Ivanovich Volkov 1, 2
Vitaly Ivanovich Volkov
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 Scienific Center in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
10.1016/j.mencom.2023.02.021
Published 2023-02-13
Communication , Volume 33, Issue 2, 215-217
3
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Slesarenko N. A. et al. Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 215-217.
GOST all authors (up to 50) Copy
Slesarenko N. A., Chernyak A. V., Avilova I. A., Tarasov V. P., Volkov V. I. Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 215-217.
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TY - JOUR
DO - 10.1016/j.mencom.2023.02.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.021
TI - Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques
T2 - Mendeleev Communications
AU - Slesarenko, Nikita Andreevich
AU - Chernyak, Alexander Vladimirovich
AU - Avilova, Irina Alekseevna
AU - Tarasov, Victor Petrovich
AU - Volkov, Vitaly Ivanovich
PY - 2023
DA - 2023/02/13
PB - Mendeleev Communications
SP - 215-217
IS - 2
VL - 33
ER -
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@article{2023_Slesarenko,
author = {Nikita Andreevich Slesarenko and Alexander Vladimirovich Chernyak and Irina Alekseevna Avilova and Victor Petrovich Tarasov and Vitaly Ivanovich Volkov},
title = {Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.021},
number = {2},
pages = {215--217},
doi = {10.1016/j.mencom.2023.02.021}
}
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Slesarenko, Nikita Andreevich, et al. “Mobility of Li+, Na+, and Cs+ cations in Nafion membrane, as studied by NMR techniques.” Mendeleev Communications, vol. 33, no. 2, Feb. 2023, pp. 215-217. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.021.

Keywords

and cesium cations
correlation time.
diffusion
lithium
Nafion membrane
NMR relaxation times
sodium

Abstract

The local mobility and diffusion of Li+, Na+, and Cs+ cations in Nafion 117 membrane were explored by 7Li, 23Na, and 133Cs spin relaxation and pulsed field gradient NMR techniques. It was shown that the macroscopic mass transfer of cations is controlled by ion motion near sulfonate groups. Lithium and sodium cations, whose hydrated energy is higher than the water hydrogen bond energy, are moving together with water molecules, but cesium cations possessing a low hydrated energy are jumping directly between the neighboring sulfonate groups.

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