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Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin

Mariya Vasil'evna Tesakova 1
Mariya Vasil'evna Tesakova
, 
Sergei Aleksandrovich Syrbu 1
Sergei Aleksandrovich Syrbu
, 
Vladimir Ivanovich Parfenyuk 1
Vladimir Ivanovich Parfenyuk
1 G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russian Federation
10.1016/j.mencom.2023.01.028
Published 2022-12-26
Communication , Volume 33, Issue 1, 90-92
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Tesakova M. V., Syrbu S. A., Parfenyuk V. I. Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 90-92.
GOST all authors (up to 50) Copy
Tesakova M. V., Syrbu S. A., Parfenyuk V. I. Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 90-92.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.028
TI - Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin
T2 - Mendeleev Communications
AU - Tesakova, Mariya Vasil'evna
AU - Syrbu, Sergei Aleksandrovich
AU - Parfenyuk, Vladimir Ivanovich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 90-92
IS - 1
VL - 33
ER -
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@article{2022_Tesakova,
author = {Mariya Vasil'evna Tesakova and Sergei Aleksandrovich Syrbu and Vladimir Ivanovich Parfenyuk},
title = {Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.028},
number = {1},
pages = {90--92},
doi = {10.1016/j.mencom.2023.01.028}
}
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Tesakova, Mariya Vasil'evna, et al. “Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 90-92. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.028.
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Keywords

5 10 15 20-tetra(4-pyridyl)porphyrin
electropolymerization
IR spectra
optical band gap.
polyporphyrin films
UV-VIS spectra

Abstract

Polyporphyrin films were obtained by electrooxidative polymerization of 5,10,15,20-tetra(4-pyridyl)porphyrin which, in turn, was obtained by condensation of pyrrole with pyridine-4-carboxaldehyde. The polymer formation involved the side substituents, with the π-conjugated porphyrin platform being preserved. The obtained polyporphyrin forms an electroconductive coating possessing semiconductor properties with the band gap of 1.76 eV

References

.
Abdulaeva I.A., Polivanovskaia D.A., Birin K.P., Gorbunova Y.G., Tsivadze A.Y.
Mendeleev Communications, 2020
.
Optical Properties and Electronic Structure of Amorphous Germanium
Tauc J., Grigorovici R., Vancu A.
Physica Status Solidi (B): Basic Research, 1966
.
Photoluminescence and Transient Spectroscopy of Free Base Porphyrin Aggregates
Khairutdinov R.F., Serpone N.
Journal of Physical Chemistry B, 1999
.
Electrochemical behavior of a number of bispyridyl-substituted porphyrins and their electrocatalytic activity in molecular oxygen reduction reaction
Do M.N., Berezina N.M., Bazanov M.I., Gyseinov S.S., Berezin M.M., Koifman O.I.
Journal of Porphyrins and Phthalocyanines, 2016
.
Synthesis, structures, and photoluminescence of heteroligand complexes Ln(L)(iso-Bu2PS2)2(NO3) (Ln = Sm, Tb, Dy; L = Phen, 2,2′-Bipy)
Bryleva Y.A., Kokina T.E., Glinskaya L.A., Uskov E.M., Rakhmanova M.I., Alekseev A.V., Larionov S.V.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2012
.
A molecular photonic wire
Wagner R.W., Lindsey J.S.
Journal of the American Chemical Society, 1994
.
Thermotropic phase behaviour and aggregation properties of tetraphenylporphyrins carrying oligo(ethylene oxide) alkoxy units
Kroon J.M., Schenkels P.S., Dijk M.V., Sudhölter E.J.
Journal of Materials Chemistry A, 1995
.
Electrochemical preparation and characterization of zinc porphyrin-coated electrodes
Ramachandraiah G., Bedioui F., Devynck J., Serrar M., Bied-Charreton C.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1991
.
Catalytic Oxidation of 2-Mercaptoethanol by Cationic Water-soluble Phthalocyaninatocobalt(II) Complexes
KIMURA M., YAMAGUCHI Y., KOYAMA T., HANABUSA K., SHIRAI H.
Journal of Porphyrins and Phthalocyanines, 2002
.
Optical spectroscopy characterization of zinc tetra pyridel porphine (ZnTPyP) organic thin films
Shehata M.M., Kamal H., Hasheme H.M., El-Nahass M.M., Abdelhady K.
Optics and Laser Technology, 2018
.
Kuzmin S.M., Chulovskaya S.A., Parfenyuk V.I., Koifman O.I.
Mendeleev Communications, 2019
.
Influence of X-ray irradiation on the optical properties of CoMTPP thin films
El-Nahass M.M., Ammar A.H., Atta A.A., Farag A.A., El-Zaidia E.F.
Optics Communications, 2011
.
Influence of X-ray irradiation on the optical properties of iron (III) chloride tetraphenylporphyrin thin films
El-Nahass M.M., El-Deeb A.F., Metwally H.S., El-Sayed H.E., Hassanien A.M.
Solid State Sciences, 2010
.
Kuzmin S.M., Chulovskaya S.A., Parfenyuk V.I., Koifman O.I.
Mendeleev Communications, 2020
.
Electropreparation and characterization of polyNiTSPc films. An EQCM study
Ureta-Zañartu M.S., Alarcón A., Berríos C., Cárdenas-Jirón G.I., Zagal J., Gutiérrez C.
Journal of Electroanalytical Chemistry, 2005
.
Electrooxidation of 2-chlorophenol on polyNiTSPc-modified glassy carbon electrodes
Ureta-Zañartu M.S., Berrı́os C., Pavez J., Zagal J., Gutiérrez C., Marco J.F.
Journal of Electroanalytical Chemistry, 2003
.
Electroconductive films based on amino-substituted tetraphenylporphyrins and their metal copper complexes
Tesakova M.V., Semeikin A.S., Parfenyuk V.I.
Journal of Porphyrins and Phthalocyanines, 2016