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New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics

Svetlana Petrovna Petrosyants 1
Svetlana Petrovna Petrosyants
, 
Andrei Borisovich Ilyukhin 1
Andrei Borisovich Ilyukhin
, 
Konstantin Andreevich Babeshkin 1
Konstantin Andreevich Babeshkin
,  , 
Pavel Sergeevich Koroteev 1
Pavel Sergeevich Koroteev
10.1016/j.mencom.2023.01.013
Published 2022-12-26
Communication , Volume 33, Issue 1, 45-46
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Petrosyants S. P. et al. New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 45-46.
GOST all authors (up to 50) Copy
Petrosyants S. P., Ilyukhin A. B., Babeshkin K. A., Efimov N. N., Koroteev P. S. New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 45-46.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.013
TI - New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics
T2 - Mendeleev Communications
AU - Petrosyants, Svetlana Petrovna
AU - Ilyukhin, Andrei Borisovich
AU - Babeshkin, Konstantin Andreevich
AU - Efimov, Nikolai Nikolaevich
AU - Koroteev, Pavel Sergeevich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 45-46
IS - 1
VL - 33
ER -
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@article{2022_Petrosyants,
author = {Svetlana Petrovna Petrosyants and Andrei Borisovich Ilyukhin and Konstantin Andreevich Babeshkin and Nikolai Nikolaevich Efimov and Pavel Sergeevich Koroteev},
title = {New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.013},
number = {1},
pages = {45--46},
doi = {10.1016/j.mencom.2023.01.013}
}
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Petrosyants, Svetlana Petrovna, et al. “New chain polymer [Yb(tpa)(H2O)2Co(CN)6]n · 7n H2O: synthesis, structure, and magnetic characteristics.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 45-46. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.013.
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Keywords

coordination polymers
cyanometallate chains
heterometallic complexes
single-molecule magnets.
ytterbium

Abstract

The 3d- 4f heterometallic polymeric complex, namely [Yb(tpa)(H2O)2Co(CN)6]n·7n H2O [tpa = tris(2-pyridylmethyl)- amine], was synthesized and characterized. Its polymer structure is formed of [Yb(tpa)(H2O)2Co(CN)6] chains and crystallization water molecules with a two-capped trigonal prism Yb3+ coordination polyhedron; the Yb3+ coordination number is 8, and the coordination site is YbN6O2. Magnetic characteristics indicate that the complex exhibits the properties of a single-chain magnet with a magnetization reversal barrier(!E/kB) of 42 K.

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