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Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand

Pavel Alekseevich Petrov 1
Pavel Alekseevich Petrov
, 
Alexander Valeryevich Rogachev 1
Alexander Valeryevich Rogachev
, 
Taisiya Sergeevna Sukhikh 1
Taisiya Sergeevna Sukhikh
, 
Ilia Vladimirovich Eltsov 2
Ilia Vladimirovich Eltsov
, 
Pavel Aleksandrovich Abramov 1
Pavel Aleksandrovich Abramov
, 
Maksim Nail'evich Sokolov 1
Maksim Nail'evich Sokolov
10.1016/j.mencom.2022.09.003
Published 2022-09-05
Communication , Volume 32, Issue 5, 579-581
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Petrov P. A. et al. Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 579-581.
GOST all authors (up to 50) Copy
Petrov P. A., Rogachev A. V., Sukhikh T. S., Eltsov I. V., Abramov P. A., Sokolov M. N. Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 579-581.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.003
TI - Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand
T2 - Mendeleev Communications
AU - Petrov, Pavel Alekseevich
AU - Rogachev, Alexander Valeryevich
AU - Sukhikh, Taisiya Sergeevna
AU - Eltsov, Ilia Vladimirovich
AU - Abramov, Pavel Aleksandrovich
AU - Sokolov, Maksim Nail'evich
PY - 2022
DA - 2022/09/05
PB - Mendeleev Communications
SP - 579-581
IS - 5
VL - 32
ER -
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@article{2022_Petrov,
author = {Pavel Alekseevich Petrov and Alexander Valeryevich Rogachev and Taisiya Sergeevna Sukhikh and Ilia Vladimirovich Eltsov and Pavel Aleksandrovich Abramov and Maksim Nail'evich Sokolov},
title = {Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.003},
number = {5},
pages = {579--581},
doi = {10.1016/j.mencom.2022.09.003}
}
MLA
Cite this
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Petrov, Pavel Alekseevich, et al. “Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 579-581. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.09.003.

Keywords

amides
carbon disulfide
dithiocarbamates
pyrazolates
sulfides
tantalum complexes

Abstract

The reaction beetwen tantalum pentakis(3,5-dimethyl-pyrazolate) and CS2 afforded novel complex [Ta(=S)(dmpz)2{(dmpz)3CS}]. In this reaction the molecule of CS2 undergoes scission with the migration of one sulfide to the tantalum atom while three pyrazolate residues migrate to carbon with the formation of unusual (dmpz)3CS– ligand. The structure of the product was established by X-ray diffraction.

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