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Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol

Julia Alexandrovna Zakharova 1
Julia Alexandrovna Zakharova
, 
Maria Fridrihovna Zansokhova 1
Maria Fridrihovna Zansokhova
, 
Evgeny Alexandrovich Karpushkin 1
Evgeny Alexandrovich Karpushkin
, 
Vladimir Glebovich Sergeyev 1
Vladimir Glebovich Sergeyev
10.1016/j.mencom.2021.11.023
Published 2021-11-08
Communication , Volume 31, Issue 6, 839-841
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Zakharova J. A. et al. Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 839-841.
GOST all authors (up to 50) Copy
Zakharova J. A., Zansokhova M. F., Karpushkin E. A., Sergeyev V. G. Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 839-841.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.023
TI - Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol
T2 - Mendeleev Communications
AU - Zakharova, Julia Alexandrovna
AU - Zansokhova, Maria Fridrihovna
AU - Karpushkin, Evgeny Alexandrovich
AU - Sergeyev, Vladimir Glebovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 839-841
IS - 6
VL - 31
ER -
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@article{2021_Zakharova,
author = {Julia Alexandrovna Zakharova and Maria Fridrihovna Zansokhova and Evgeny Alexandrovich Karpushkin and Vladimir Glebovich Sergeyev},
title = {Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.023},
number = {6},
pages = {839--841},
doi = {10.1016/j.mencom.2021.11.023}
}
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Zakharova, Julia Alexandrovna, et al. “Significant improving H+/VO2+ permselectivity of Nafion membrane by modification with PDDA in aqueous isopropanol.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 839-841. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.023.

Keywords

Bradford reagent
isopropanol
Nafion membrane
PDDA
proton conductivity
vanadyl permeability

Abstract

The modification of Nafion® membranes with poly(diallyldimethylammonium chloride) (PDDA) in aqueous solutions of isopropanol has been investigated. A remarkable decrease in vanadyl ion permeability (by 3.5 orders of magnitude), accompanied by a decrease in proton conductivity sixfold at most, was found for Nafion membranes modified in 30–35 wt% isopropanol solutions providing a high swelling of the membranes. The Bradford reagent has been used for the detection of PDDA on the membrane surface.

References

1.
Review of material research and development for vanadium redox flow battery applications
Parasuraman A., Lim T.M., Menictas C., Skyllas-Kazacos M.
Electrochimica Acta, 2013
2.
Recent development of membrane for vanadium redox flow battery applications: A review
Shi Y., Eze C., Xiong B., He W., Zhang H., Lim T.M., Ukil A., Zhao J.
Applied Energy, 2019
3.
State of Understanding of Nafion
Mauritz K.A., Moore R.B.
Chemical Reviews, 2004
4.
The morphology in nafion perfluorinated membrane products, as determined by wide- and small-angle x-ray studies
Gierke T.D., Munn G.E., Wilson F.C.
Journal of Polymer Science Part C: Polymer Letters, 1981
6.
Small-angle neutron scattering investigation of structural changes in nafion membranes induced by swelling with various solvents
Young S.K., Trevino S.F., Beck Tan N.C.
Journal of Polymer Science, Part B: Polymer Physics, 2002
7.
10.1016/j.mencom.2021.11.023_b0035
Jeon
Energy Mater., 2020
8.
Controlled modification of Nafion membrane with cationic surfactant
Zakharova J.A., Novoskoltseva O.A., Pyshkina O.A., Karpushkin E.A., Sergeyev V.G.
Colloid and Polymer Science, 2018
9.
Recent Development in Composite Membranes for Flow Batteries
Wu J., Dai Q., Zhang H., Li X.
ChemSusChem, 2020
10.
Membranes for all vanadium redox flow batteries
Tempelman C.H., Jacobs J.F., Balzer R.M., Degirmenci V.
Journal of Energy Storage, 2020
11.
Redox Flow Battery Membranes: Improving Battery Performance by Leveraging Structure–Property Relationships
Machado C.A., Brown G.O., Yang R., Hopkins T.E., Pribyl J.G., Epps T.H.
ACS Energy Letters, 2020
12.
Prospects of Membrane Science Development
Apel P.Y., Bobreshova O.V., Volkov A.V., Volkov V.V., Nikonenko V.V., Stenina I.A., Filippov A.N., Yampolskii Y.P., Yaroslavtsev A.B.
Membranes and Membrane Technologies, 2019
14.
2H NMR Studies of Polymer Multilayer Capsules, Films, and Complexes
Fortier-McGill B., Reven L.
Macromolecules, 2008
15.
Modification of Nafion membrane by polyaniline providing uniform polymer distribution throughout the membrane
Pyshkina О.А., Novoskoltseva О.А., Zakharova J.A.
Colloid and Polymer Science, 2018
16.
Swelling Properties of Ion‐Exchange Membranes in Contact with Water–Alcohol Mixtures
Kujawski W., Poźniak G.
Separation Science and Technology, 2005
17.
10.1016/j.mencom.2021.11.023_b0085
Zawodzinski
J. Electrochem. Soc., 1981
18.
Sulfonated poly (ether ether ketone)-based proton exchange membranes for vanadium redox battery applications
Winardi S., Raghu S.C., Oo M.O., Yan Q., Wai N., Lim T.M., Skyllas-Kazacos M.
Journal of Membrane Science, 2014
22.
Anti-microbial approach onto cationic-exchange membranes
Pontié M., Ben Rejeb S., Legrand J.
Separation and Purification Technology, 2012