Home / Publications / Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase

Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase

Mikhail Vladimirovich Korolenko 1
Mikhail Vladimirovich Korolenko
, 
Pavel Borisovich Fabrichnyi 1
Pavel Borisovich Fabrichnyi
, 
10.1016/j.mencom.2021.07.045
Published 2021-07-07
Communication , Volume 31, Issue 4, 570-571
5
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Korolenko M. V., Fabrichnyi P. B., Afanasov M. I. Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 570-571.
GOST all authors (up to 50) Copy
Korolenko M. V., Fabrichnyi P. B., Afanasov M. I. Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 570-571.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.07.045
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.045
TI - Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase
T2 - Mendeleev Communications
AU - Korolenko, Mikhail Vladimirovich
AU - Fabrichnyi, Pavel Borisovich
AU - Afanasov, Mikhail Ivanovich
PY - 2021
DA - 2021/07/07
PB - Mendeleev Communications
SP - 570-571
IS - 4
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Korolenko,
author = {Mikhail Vladimirovich Korolenko and Pavel Borisovich Fabrichnyi and Mikhail Ivanovich Afanasov},
title = {Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.045},
number = {4},
pages = {570--571},
doi = {10.1016/j.mencom.2021.07.045}
}
MLA
Cite this
MLA Copy
Korolenko, Mikhail Vladimirovich, et al. “Effects of Sn4+ dopant ions located either in the bulk or at crystallite surfaces on the ultraviolet photocatalytic activity of anatase.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 570-571. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.045.

Abstract

Isovalent Sn4+ dopant cations do not have a significant effect on the ultraviolet photocatalytic activity of anatase (TiO2) regardless of their location in the bulk or at the surfaces of crystallites. This is due to the formation of no charge balance oxygen vacancies VO acting as (e–,h+) recombination centers towards photogenerated electrons and holes upon doping with Sn4+. Nevertheless, the analysis of a sample containing surfacelocated heterovalent Sb3+ ions (isoelectronic with Sn2+) revealed a significant weakening of the negative effect of VO, which can be accounted for by the presence of a stereochemically active lone pair E of 5s electrons in the nearest vicinity of VO.

References

1.
Successful location of tin dopant cations on surface sites of anatase-type TiO2 crystallites evidenced by 119Sn Mössbauer spectroscopic probe and XPS techniques
Astashkin R.A., Fabritchnyi P.B., Afanasov M.I., Korolenko M.V., Wattiaux A., Bordère S., Labrugère C., Delmas C.
Solid State Sciences, 2013
2.
10.1016/j.mencom.2021.07.045_b0010
Yadav
J. Mater. Sci.: Mater. Electron., 2016
3.
Photocatalysis with Chromium-Doped TiO2: Bulk and Surface Doping
Ould-Chikh S., Proux O., Afanasiev P., Khrouz L., Hedhili M.N., Anjum D.H., Harb M., Geantet C., Basset J., Puzenat E.
ChemSusChem, 2014
4.
Photoinduced Dynamics of TiO2 Doped with Cr and Sb
Ikeda T., Nomoto T., Eda K., Mizutani Y., Kato H., Kudo A., Onishi H.
Journal of Physical Chemistry C, 2008
5.
Transition metal dopedTiO2: physical properties and photocatalytic behaviour
Paola A.D., Ikeda S., Marcì G., Ohtani B., Palmisano L.
International Journal of Photoenergy, 2001
6.
Korolenko M.V., Fabritchnyi P.B., Afanasov M.I.
Mendeleev Communications, 2020
7.
Manifestation of the photocatalytic activity of anatase powders in Mössbauer spectra of 121Sb probe nuclei
Korolenko M.V., Fabrichnyi P.B., Afanasov M.I., Labrugère C.
Bulletin of the Russian Academy of Sciences: Physics, 2015
8.
121Sb Mössbauer spectra of antimony oxides
Long G.G., Stevens J.G., Bowen L.H.
Inorganic and Nuclear Chemistry Letters, 1969