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Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes

Liang Wang 1
Liang Wang
, 
Yaoyao Wang 2
Yaoyao Wang
, 
Yu Tao 1
Yu Tao
, 
Nana Zhang 1
Nana Zhang
, 
Shubai Li 1
Shubai Li
1 School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
10.1016/j.mencom.2021.03.043
Published 2021-03-03
Communication , Volume 31, Issue 2, 271-273
3
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Wang L. et al. Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 271-273.
GOST all authors (up to 50) Copy
Wang L., Wang Y., Tao Yu., Zhang N., Li S. Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 271-273.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.043
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.043
TI - Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes
T2 - Mendeleev Communications
AU - Wang, Liang
AU - Wang, Yaoyao
AU - Tao, Yu
AU - Zhang, Nana
AU - Li, Shubai
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 271-273
IS - 2
VL - 31
ER -
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@article{2021_Wang,
author = {Liang Wang and Yaoyao Wang and Yu Tao and Nana Zhang and Shubai Li},
title = {Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.043},
number = {2},
pages = {271--273},
doi = {10.1016/j.mencom.2021.03.043}
}
MLA
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MLA Copy
Wang, Liang, et al. “Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 271-273. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.043.

Keywords

aldehydes
arenecarboxylic acids
C–O cleavage
dimethyl dicarbonate
hydrosilanes
nickel catalysis

Abstract

Nickel-catalyzed reduction of (het)arenecarboxylic acids with hydrosilanes in the presence of dimethyl dicarbonate as the activator affords the corresponding aldehydes. The role of the activator is the conversion of the acids into their anhydrides undergoing C–O cleavage. The good yields were achieved in case of substrates bearing electron-donating and electron-neutral groups.

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