Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts

Vinogradov, Dmitriy Borisovitsh; Bulatov, Pavel Valeryevich; Petrov, Evgeny Yuryevich; Tartakovsky, Vladimir Alexandrovich

doi:10.1016/j.mencom.2020.11.031

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Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts

Dmitriy Borisovitsh Vinogradov ¹

Dmitriy Borisovitsh Vinogradov

,

Pavel Valeryevich Bulatov ¹

Pavel Valeryevich Bulatov

,

Evgeny Yuryevich Petrov ¹

Evgeny Yuryevich Petrov

,

Vladimir Alexandrovich Tartakovsky ¹

Vladimir Alexandrovich Tartakovsky

0000-0002-2535-0539

¹ N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2020.11.031

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Published 2020-11-03

Communication , Volume 30, Issue 6, 781-784

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Vinogradov D. B. et al. Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 781-784.

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Vinogradov D. B., Bulatov P. V., Petrov E. Y., Tartakovsky V. A. Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 781-784.

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TY - JOUR

DO - 10.1016/j.mencom.2020.11.031

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.031

TI - Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts

T2 - Mendeleev Communications

AU - Vinogradov, Dmitriy Borisovitsh

AU - Bulatov, Pavel Valeryevich

AU - Petrov, Evgeny Yuryevich

AU - Tartakovsky, Vladimir Alexandrovich

PY - 2020

DA - 2020/11/03

PB - Mendeleev Communications

SP - 781-784

IS - 6

VL - 30

ER -

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@article{2020_Vinogradov,

author = {Dmitriy Borisovitsh Vinogradov and Pavel Valeryevich Bulatov and Evgeny Yuryevich Petrov and Vladimir Alexandrovich Tartakovsky},

title = {Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts},

journal = {Mendeleev Communications},

year = {2020},

volume = {30},

publisher = {Mendeleev Communications},

month = {Nov},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.031},

number = {6},

pages = {781--784},

doi = {10.1016/j.mencom.2020.11.031}

}

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Vinogradov, Dmitriy Borisovitsh, et al. “Heterocyclization of amino alcohols into saturated cyclic quaternary ammonium salts.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 781-784. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.031.

Keywords

aldehydes

amino alcohols

ammonium quaternary salts

heterocyclization

nitramines

nitrates

Abstract

Cyclodehydration of available N-alkylethanolamines with aldehydes and simultaneous or subsequent quaternization afford functionalized quaternary ammonium salts of N-nitroimidazolidine, oxazolidine and annulated bismorpholine type. Further replacement of their anions with residues of explosive acids provides a series of energyintensive quaternary salts with a rich hydrogen content possessing satisfactory energy characteristics and sufficiently high thermal stability.

References

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