Keywords
actuator systems
cyclic voltammetry
metallatranes
organogermanium compounds
radical cations
redox properties
Abstract
Bis-phenyl derivative of a novel family of bis-metallatranes, 1,1′-diphenyl-bis-germatrane, was synthesized and characterized. One-electron oxidation of this compound is electrochemically and chemically reversible providing a persistent radical cation.
References
1.
Verkade J.G.
Coordination Chemistry Reviews,
1994
2.
10.1016/j.mencom.2020.09.004_sbref0005b
Baukov
2002
3.
Peureux C., Jouikov V.
Chemistry - A European Journal,
2014
4.
Ignatovich L., Jouikov V.
Journal of Organometallic Chemistry,
2014
5.
Sidorkin V.F., Belogolova E.F., Wang Y., Jouikov V., Doronina E.P.
Chemistry - A European Journal,
2017
6.
Jouikov V., Romanovs V., Spura J.
Synthesis,
2018
7.
Jie Y., Livant P., Li H., Yang M., Zhu W., Cammarata V., Almond P., Sullens T., Qin Y., Bakker E.
Journal of Organic Chemistry,
2010
8.
10.1016/j.mencom.2020.09.004_bib0035
Bard
Electrochemical Methods: Fundamentals and Applications,
2001
9.
Mendkovich A.S., Luzhkov V.B., Syroeshkin M.A., Sen´ V.D., Khartsii D.I., Rusakov A.I.
Russian Chemical Bulletin,
2017
10.
Syroeshkin M.A., Mikhailov M.N., Mendkovich A.S., Rusakov A.I.
Russian Chemical Bulletin,
2009
11.
Okano M., Mochida K.
Bulletin of the Chemical Society of Japan,
1991
12.
Broka K., Stradiņš J., Glezer V., Zelčāns G., Lukevics E.
Journal of Electroanalytical Chemistry,
1993