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3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources

, 
Guzaliya Rafikovna Baymuratova 1
Guzaliya Rafikovna Baymuratova
, 
Igor Konstantinovich Yakushchenko 1
Igor Konstantinovich Yakushchenko
, 
Galiya Zaynetdinovna Tulibaeva 1
Galiya Zaynetdinovna Tulibaeva
, 
Alexander Fedorovich Shestakov 1, 2
Alexander Fedorovich Shestakov
, 
10.1016/j.mencom.2020.01.026
Published 2019-12-30
Communication , Volume 30, Issue 1, 78-80
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Slesarenko A. A. et al. 3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 78-80.
GOST all authors (up to 50) Copy
Slesarenko A. A., Baymuratova G. R., Yakushchenko I. K., Tulibaeva G. Z., Shestakov A. F., Yarmolenko O. V. 3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources // Mendeleev Communications. 2019. Vol. 30. No. 1. pp. 78-80.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.026
TI - 3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources
T2 - Mendeleev Communications
AU - Slesarenko, Anna Alekseevna
AU - Baymuratova, Guzaliya Rafikovna
AU - Yakushchenko, Igor Konstantinovich
AU - Tulibaeva, Galiya Zaynetdinovna
AU - Shestakov, Alexander Fedorovich
AU - Yarmolenko, Ol'ga Viktorovna
PY - 2019
DA - 2019/12/30
PB - Mendeleev Communications
SP - 78-80
IS - 1
VL - 30
ER -
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@article{2019_Slesarenko,
author = {Anna Alekseevna Slesarenko and Guzaliya Rafikovna Baymuratova and Igor Konstantinovich Yakushchenko and Galiya Zaynetdinovna Tulibaeva and Alexander Fedorovich Shestakov and Ol'ga Viktorovna Yarmolenko},
title = {3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources},
journal = {Mendeleev Communications},
year = {2019},
volume = {30},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.026},
number = {1},
pages = {78--80},
doi = {10.1016/j.mencom.2020.01.026}
}
MLA
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Slesarenko, Anna Alekseevna, et al. “3-Pentadecyl-2,4-dioxo-16-crown-5 as a promising additive in electrolytes for chemical power sources.” Mendeleev Communications, vol. 30, no. 1, Dec. 2019, pp. 78-80. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.01.026.

Keywords

charge-discharge cycling
crown ethers
electrochemical impedance
lithium battery
lithium ferro phosphate cathode.
lithium ions
organic electrolyte
quantum-chemical modeling

Abstract

A new crown ether, 3-pentadecyl-2,4-dioxo-16-crown-5, with surfactant properties has been synthesized in three simple steps from diethyl pentadecylmalonate. Quantum chemical calculations show that this crown ether is capable of adsorbing both on the surface of the lithium anode and on the surface of carbon. The effectiveness of its application as a functional additive in organic electrolyte for lithium batteries has been experimentally confirmed.

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