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Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene

Anastasiya Alekseevna Shesterkina 1
Anastasiya Alekseevna Shesterkina
, 
Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Elena Vladimirovna Shuvalova 1
Elena Vladimirovna Shuvalova
, 
Gennady Ivanovich Kapustin 1
Gennady Ivanovich Kapustin
, 
Vladimir Borisovich Kazanskii 1
Vladimir Borisovich Kazanskii
, 
Leonid Modestovich Kustov 1, 2
Leonid Modestovich Kustov
10.1016/j.mencom.2019.11.021
Published 2019-11-01
Communication , Volume 29, Issue 6, 666-668
7
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Shesterkina A. A. et al. Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 666-668.
GOST all authors (up to 50) Copy
Shesterkina A. A., Tkachenko O. P., Shuvalova E. V., Kapustin G. I., Kazanskii V. B., Kustov L. M. Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene // Mendeleev Communications. 2019. Vol. 29. No. 6. pp. 666-668.
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TY - JOUR
DO - 10.1016/j.mencom.2019.11.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.021
TI - Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene
T2 - Mendeleev Communications
AU - Shesterkina, Anastasiya Alekseevna
AU - Tkachenko, Olga P.
AU - Shuvalova, Elena Vladimirovna
AU - Kapustin, Gennady Ivanovich
AU - Kazanskii, Vladimir Borisovich
AU - Kustov, Leonid Modestovich
PY - 2019
DA - 2019/11/01
PB - Mendeleev Communications
SP - 666-668
IS - 6
VL - 29
ER -
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@article{2019_Shesterkina,
author = {Anastasiya Alekseevna Shesterkina and Olga P. Tkachenko and Elena Vladimirovna Shuvalova and Gennady Ivanovich Kapustin and Vladimir Borisovich Kazanskii and Leonid Modestovich Kustov},
title = {Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.021},
number = {6},
pages = {666--668},
doi = {10.1016/j.mencom.2019.11.021}
}
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Shesterkina, Anastasiya Alekseevna, et al. “Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene.” Mendeleev Communications, vol. 29, no. 6, Nov. 2019, pp. 666-668. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.11.021.

Abstract

Iron-modified platinum bimetallic system, 1% Pt–1% Fe/SiO2, provides selective liquid-phase hydrogenation of phenylacetylene into styrene at 70°C and 5 atm. This effect is attributed to the electron enrichment of the Pt surface atoms due to a charge transfer from Fe to Pt or contact interactions between these two metals, as indicated by XPS and DRIFTS-CO.

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