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Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids

Anatoly Nikolaevich Vereshchagin 1
Anatoly Nikolaevich Vereshchagin
, 
Evgeniya Olegovna Dorofeeva 1
Evgeniya Olegovna Dorofeeva
,  , 
Viktor Alfredovich Korolev 1
Viktor Alfredovich Korolev
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2019.07.010
Published 2019-07-01
Communication , Volume 29, Issue 4, 391-392
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Vereshchagin A. N. et al. Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 391-392.
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Vereshchagin A. N., Dorofeeva E. O., Elinson M. N., Korolev V. A., Egorov M. P. Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids // Mendeleev Communications. 2019. Vol. 29. No. 4. pp. 391-392.
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TY - JOUR
DO - 10.1016/j.mencom.2019.07.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.010
TI - Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids
T2 - Mendeleev Communications
AU - Vereshchagin, Anatoly Nikolaevich
AU - Dorofeeva, Evgeniya Olegovna
AU - Elinson, Michail Nikolaevich
AU - Korolev, Viktor Alfredovich
AU - Egorov, Mikhail Petrovich
PY - 2019
DA - 2019/07/01
PB - Mendeleev Communications
SP - 391-392
IS - 4
VL - 29
ER -
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@article{2019_Vereshchagin,
author = {Anatoly Nikolaevich Vereshchagin and Evgeniya Olegovna Dorofeeva and Michail Nikolaevich Elinson and Viktor Alfredovich Korolev and Mikhail Petrovich Egorov},
title = {Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.010},
number = {4},
pages = {391--392},
doi = {10.1016/j.mencom.2019.07.010}
}
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Vereshchagin, Anatoly Nikolaevich, et al. “Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids.” Mendeleev Communications, vol. 29, no. 4, Jul. 2019, pp. 391-392. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.07.010.

Abstract

Pyridinium bromide has been tested as a new mediator for electrochemical synthesis of functionalized cyclopropane from alkylidenemalononitriles and CH-acids. The process was performed in an undivided cell with the use of substoichiometric amount of PyHBr that serves both as a mediator and a supporting electrolyte, and MeOH or MeCN as the solvents.

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