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Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions

Anastasiya Alekseevna Shesterkina 1
Anastasiya Alekseevna Shesterkina
, 
Lyudmila Mikhailovna Kozlova 1
Lyudmila Mikhailovna Kozlova
, 
Igor Vladimirovich Mishin 1
Igor Vladimirovich Mishin
, 
Olga P. Tkachenko 1
Olga P. Tkachenko
, 
Gennady Ivanovich Kapustin 1
Gennady Ivanovich Kapustin
, 
Viktor Petrovich Zakharov 2
Viktor Petrovich Zakharov
, 
Mikhail Sergeevich Vlaskin 2
Mikhail Sergeevich Vlaskin
, 
Andrei Zinov'evich Zhuk 2
Andrei Zinov'evich Zhuk
, 
Olga Alekseevna Kirichenko 1
Olga Alekseevna Kirichenko
, 
Leonid Modestovich Kustov 1, 3
Leonid Modestovich Kustov
10.1016/j.mencom.2019.05.034
Published 2019-04-26
Communication , Volume 29, Issue 3, 339-342
16
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Shesterkina A. A. et al. Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 339-342.
GOST all authors (up to 50) Copy
Shesterkina A. A., Kozlova L. M., Mishin I. V., Tkachenko O. P., Kapustin G. I., Zakharov V. P., Vlaskin M. S., Zhuk A. Z., Kirichenko O. A., Kustov L. M. Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions // Mendeleev Communications. 2019. Vol. 29. No. 3. pp. 339-342.
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TY - JOUR
DO - 10.1016/j.mencom.2019.05.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.034
TI - Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions
T2 - Mendeleev Communications
AU - Shesterkina, Anastasiya Alekseevna
AU - Kozlova, Lyudmila Mikhailovna
AU - Mishin, Igor Vladimirovich
AU - Tkachenko, Olga P.
AU - Kapustin, Gennady Ivanovich
AU - Zakharov, Viktor Petrovich
AU - Vlaskin, Mikhail Sergeevich
AU - Zhuk, Andrei Zinov'evich
AU - Kirichenko, Olga Alekseevna
AU - Kustov, Leonid Modestovich
PY - 2019
DA - 2019/04/26
PB - Mendeleev Communications
SP - 339-342
IS - 3
VL - 29
ER -
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@article{2019_Shesterkina,
author = {Anastasiya Alekseevna Shesterkina and Lyudmila Mikhailovna Kozlova and Igor Vladimirovich Mishin and Olga P. Tkachenko and Gennady Ivanovich Kapustin and Viktor Petrovich Zakharov and Mikhail Sergeevich Vlaskin and Andrei Zinov'evich Zhuk and Olga Alekseevna Kirichenko and Leonid Modestovich Kustov},
title = {Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.034},
number = {3},
pages = {339--342},
doi = {10.1016/j.mencom.2019.05.034}
}
MLA
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Shesterkina, Anastasiya Alekseevna, et al. “Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions.” Mendeleev Communications, vol. 29, no. 3, Apr. 2019, pp. 339-342. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.05.034.

Abstract

Novel promising Fe–Pd/γ-Al2O3 catalysts for the selective liquid-phase hydrogenation of unsaturated compounds (phenylacetylene and 2-methylbut-3-yn-2-ol) under ambient conditions have been prepared. They were characterized by low temperature nitrogen adsorption, XRD, SEM, TEM, TPR-H2 and DRIFTS-CO techniques. The presence of Pd–Fe nanoparticles led to increased reactivity and selectivity of the new catalysts in hydrogenation of the C≡C bond to the C=C one as compared to those of the Pd/Al2O3 system.

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