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Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols

Alexander Olegovich Terent'ev 1, 2
Alexander Olegovich Terent'ev
,  , 
Alexey Igorevich Ilovaisky 1
Alexey Igorevich Ilovaisky
, 
Vladimir Alekseevich Kokorekin 1, 3
Vladimir Alekseevich Kokorekin
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1016/j.mencom.2019.01.027
Published 2018-12-28
Communication , Volume 29, Issue 1, 80-82
22
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Terent'ev A. O. et al. Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 80-82.
GOST all authors (up to 50) Copy
Terent'ev A. O., Mulina O. M., Ilovaisky A. I., Kokorekin V. A., Nikishin G. I. Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols // Mendeleev Communications. 2018. Vol. 29. No. 1. pp. 80-82.
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TY - JOUR
DO - 10.1016/j.mencom.2019.01.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.027
TI - Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols
T2 - Mendeleev Communications
AU - Terent'ev, Alexander Olegovich
AU - Mulina, Olga Mikhailovna
AU - Ilovaisky, Alexey Igorevich
AU - Kokorekin, Vladimir Alekseevich
AU - Nikishin, Gennady Ivanovich
PY - 2018
DA - 2018/12/28
PB - Mendeleev Communications
SP - 80-82
IS - 1
VL - 29
ER -
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@article{2018_Terent'ev,
author = {Alexander Olegovich Terent'ev and Olga Mikhailovna Mulina and Alexey Igorevich Ilovaisky and Vladimir Alekseevich Kokorekin and Gennady Ivanovich Nikishin},
title = {Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols},
journal = {Mendeleev Communications},
year = {2018},
volume = {29},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.027},
number = {1},
pages = {80--82},
doi = {10.1016/j.mencom.2019.01.027}
}
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Terent'ev, Alexander Olegovich, et al. “Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols.” Mendeleev Communications, vol. 29, no. 1, Dec. 2018, pp. 80-82. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2019.01.027.

Abstract

Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH4I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety.

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