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On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO

Felix Yu Sharikov 1
Felix Yu Sharikov
, 
Petr S Sokolov 2
Petr S Sokolov
, 
Andrei Nikolaevich Baranov 3
Andrei Nikolaevich Baranov
, 
Vladimir L Solozhenko 2
Vladimir L Solozhenko
10.1016/j.mencom.2017.11.025
Published 2017-10-30
Communication , Volume 27, Issue 6, 613-614
6
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Sharikov F. Yu. et al. On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 613-614.
GOST all authors (up to 50) Copy
Sharikov F. Yu., Sokolov P. S., Baranov A. N., Solozhenko V. L. On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 613-614.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.025
TI - On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO
T2 - Mendeleev Communications
AU - Sharikov, Felix Yu
AU - Sokolov, Petr S
AU - Baranov, Andrei Nikolaevich
AU - Solozhenko, Vladimir L
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 613-614
IS - 6
VL - 27
ER -
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@article{2017_Sharikov,
author = {Felix Yu Sharikov and Petr S Sokolov and Andrei Nikolaevich Baranov and Vladimir L Solozhenko},
title = {On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.025},
number = {6},
pages = {613--614},
doi = {10.1016/j.mencom.2017.11.025}
}
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MLA Copy
Sharikov, Felix Yu., et al. “On the thermodynamic aspect of zinc oxide polymorphism: calorimetric study of metastable rock salt ZnO.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 613-614. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.025.

Abstract

The enthalpies of dissolution of metastable rock salt (rs-ZnO) and thermodynamically stable wurtzite (w-ZnO) polymorphs of zinc oxide in aqueous H2SO4 have been measured in direct calorimetric experiments at 303K and 0.1MPa. Based on the obtained results, the standard enthalpy of the rs-ZnO to w-ZnO phase transition, Δtr H = 11.7 ± 0.3kJ mol–1, has been determined.

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