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Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts

Ol'ga Andreevna Kizas 1
Ol'ga Andreevna Kizas
, 
Ivan Sergeyevich Chaschin 1
Ivan Sergeyevich Chaschin
, 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
, 
Fedor Mikhailovich Dolgushin 1
Fedor Mikhailovich Dolgushin
, 
Dmitrii Yuryevich Antonov 1
Dmitrii Yuryevich Antonov
, 
Lev Nikolaevich Nikitin 1
Lev Nikolaevich Nikitin
, 
10.1016/j.mencom.2017.07.016
Published 2017-06-29
Communication , Volume 27, Issue 4, 368-370
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Kizas O. A. et al. Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 368-370.
GOST all authors (up to 50) Copy
Kizas O. A., Chaschin I. S., Godovikov I. A., Dolgushin F. M., Antonov D. Y., Nikitin L. N., Khokhlov A. R. Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 368-370.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.016
TI - Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts
T2 - Mendeleev Communications
AU - Kizas, Ol'ga Andreevna
AU - Chaschin, Ivan Sergeyevich
AU - Godovikov, Ivan Alexandrovich
AU - Dolgushin, Fedor Mikhailovich
AU - Antonov, Dmitrii Yuryevich
AU - Nikitin, Lev Nikolaevich
AU - Khokhlov, Alexei Removich
PY - 2017
DA - 2017/06/29
PB - Mendeleev Communications
SP - 368-370
IS - 4
VL - 27
ER -
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@article{2017_Kizas,
author = {Ol'ga Andreevna Kizas and Ivan Sergeyevich Chaschin and Ivan Alexandrovich Godovikov and Fedor Mikhailovich Dolgushin and Dmitrii Yuryevich Antonov and Lev Nikolaevich Nikitin and Alexei Removich Khokhlov},
title = {Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.016},
number = {4},
pages = {368--370},
doi = {10.1016/j.mencom.2017.07.016}
}
MLA
Cite this
MLA Copy
Kizas, Ol'ga Andreevna, et al. “Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts.” Mendeleev Communications, vol. 27, no. 4, Jun. 2017, pp. 368-370. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.016.

Abstract

Cation CpFeC5H4–C+=CH2 was obtained by protonation of FcC≡CH with Nafion superacid in DMF or scCO2 and characterized by NMR spectroscopy. The protonation in the presence of SMe2 or PPh3 affords new onium derivatives, which were isolated as the tetrafluoroborate salts.

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