Home / Publications / Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond

Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond

, 
Galina Olegovna Bragina 1
Galina Olegovna Bragina
, 
Alexander Viktorovich Rassolov 1
Alexander Viktorovich Rassolov
, 
Galina Nikolaevna Baeva 1
Galina Nikolaevna Baeva
,  , 
Vadim Yur'evich Murzin 2
Vadim Yur'evich Murzin
,  , 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2016.11.014
Published 2016-10-27
Communication , Volume 26, Issue 6, 502-504
28
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Markov P. V. et al. Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 502-504.
GOST all authors (up to 50) Copy
Markov P. V., Bragina G. O., Rassolov A. V., Baeva G. N., Mashkovsky I. S., Murzin V. Y., Zubavichus Y. V., Stakheev A. Y. Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond // Mendeleev Communications. 2016. Vol. 26. No. 6. pp. 502-504.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2016.11.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.014
TI - Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond
T2 - Mendeleev Communications
AU - Markov, Pavel Viktorovich
AU - Bragina, Galina Olegovna
AU - Rassolov, Alexander Viktorovich
AU - Baeva, Galina Nikolaevna
AU - Mashkovsky, Igor' Sergeevich
AU - Murzin, Vadim Yur'evich
AU - Zubavichus, Yan Vitautasovich
AU - Stakheev, Aleksandr Yurevich
PY - 2016
DA - 2016/10/27
PB - Mendeleev Communications
SP - 502-504
IS - 6
VL - 26
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Markov,
author = {Pavel Viktorovich Markov and Galina Olegovna Bragina and Alexander Viktorovich Rassolov and Galina Nikolaevna Baeva and Igor' Sergeevich Mashkovsky and Vadim Yur'evich Murzin and Yan Vitautasovich Zubavichus and Aleksandr Yurevich Stakheev},
title = {Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond},
journal = {Mendeleev Communications},
year = {2016},
volume = {26},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.014},
number = {6},
pages = {502--504},
doi = {10.1016/j.mencom.2016.11.014}
}
MLA
Cite this
MLA Copy
Markov, Pavel Viktorovich, et al. “Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond.” Mendeleev Communications, vol. 26, no. 6, Oct. 2016, pp. 502-504. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2016.11.014.

Abstract

The formation of a PdCu alloy with an fcc structure in 1% Pd–1.2% Cu2 /Al2O3 (as evidenced by XRD and EXAFS data) significantly improves catalyst selectivity in the semihydrogenation of internal and terminal alkynes, which makes 1% Pd–1.2% Cu2 /Al2O3 a promising alternative to the commercial Lindlar catalyst.

References

1.
10.1016/j.mencom.2016.11.014_sbref0005a
Blaser
in Handbook of Heterogeneous Catalysis, 2008
2.
10.1016/j.mencom.2016.11.014_sbref0005b
Heller
2007
3.
Development of new methods in modern selective organic synthesis: Preparation of functionalized molecules with atomic precision
Ananikov V.P., Khemchyan L.L., Ivanova Y.V., Bukhtiyarov V.I., Sorokin A.M., Prosvirin I.P., Vatsadze S.Z., Medved'ko A.V., Nuriev V.N., Dilman A.D., Levin V.V., Koptyug I.V., Kovtunov K.V., Zhivonitko V.V., Likholobov V.A., et. al.
Russian Chemical Reviews, 2014
4.
Ananikov V.P., Khokhlova E.A., Egorov M.P., Sakharov A.M., Zlotin S.G., Kucherov A.V., Kustov L.M., Gening M.L., Nifantiev N.E.
Mendeleev Communications, 2015
5.
Recent advances in selective acetylene hydrogenation using palladium containing catalysts
McCue A.J., Anderson J.A.
Frontiers of Chemical Science and Engineering, 2015
6.
Catalytic hydrogenation of alkyne and alkadiene impurities from alkenes. Practical and theoretical aspects
Nikolaev S.A., Zanaveskin L.N., Smirnov V.V., Averyanov V.A., Zanaveskin K.L.
Russian Chemical Reviews, 2009
8.
Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene
Cao X., Mirjalili A., Wheeler J., Xie W., Jang B.W.
Frontiers of Chemical Science and Engineering, 2015
9.
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene
Pei G.X., Liu X.Y., Wang A., Lee A.F., Isaacs M.A., Li L., Pan X., Yang X., Wang X., Tai Z., Wilson K., Zhang T.
ACS Catalysis, 2015
13.
Mashkovsky I.S., Baeva G.N., Stakheev A.Y., Vargaftik M.N., Kozitsyna N.Y., Moiseev I.I.
Mendeleev Communications, 2014
14.
Supported catalysts based on Pd–In nanoparticles for the liquid-phase hydrogenation of terminal and internal alkynes: 1. formation and structure
Markov P.V., Bragina G.O., Baeva G.N., Tkachenko O.P., Mashkovskii I.S., Yakushev I.A., Vargaftik M.N., Stakheev A.Y.
Kinetics and Catalysis, 2016
15.
Supported catalysts based on Pd–In nanoparticles for the liquid- phase hydrogenation of terminal and internal alkynes: 2. catalytic properties
Markov P.V., Bragina G.O., Baeva G.N., Mashkovskii I.S., Rassolov A.V., Yakushev I.A., Vargaftik M.N., Stakheev A.Y.
Kinetics and Catalysis, 2016
16.
Pd-Cu catalysts from acetate complexes in liquid-phase diphenylacetylene hydrogenation
Markov P.V., Bragina G.O., Baeva G.N., Tkachenko O.P., Mashkovsky I.S., Yakushev I.A., Kozitsyna N.Y., Vargaftik M.N., Stakheev A.Y.
Kinetics and Catalysis, 2015
17.
Highly selective catalysts for liquid-phase hydrogenation of substituted alkynes based on Pd—Cu bimetallic nanoparticles
Mashkovsky I.S., Markov P.V., Bragina G.O., Tkachenko O.P., Yakushev I.A., Kozitsyna N.Y., Vargaftik M.N., Stakheev A.Y.
Russian Chemical Bulletin, 2016
19.
Kinetic Monte Carlo simulation of surface segregation in Pd–Cu alloys
Cheng F., He X., Chen Z., Huang Y.
Journal of Alloys and Compounds, 2015
20.
Optimisation of preparation method for Pd doped Cu/Al2O3 catalysts for selective acetylene hydrogenation
McCue A.J., Shepherd A.M., Anderson J.A.
Catalysis Science and Technology, 2015