Home / Articles / Synthesis and structure of nitro-substituted phosphacoumarins

Synthesis and structure of nitro-substituted phosphacoumarins

A. V. Zalaltdinova 1
A. V. Zalaltdinova
, 
Yu. M. Volodina 1
Yu. M. Volodina
,  , 
D. P. Gerasimova 1
D. P. Gerasimova
, 
E. A. Chugunova 1
E. A. Chugunova
,  ,  , 
10.71267/mencom.8136
Published 5 November 2026 , received 1 July 2026
Communication
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Zalaltdinova A. V. et al. Synthesis and structure of nitro-substituted phosphacoumarins // Mendeleev Communications. 2026.
GOST all authors (up to 50)
Copy cite
Zalaltdinova A. V., Volodina Y. M., Gazizov A. S., Gerasimova D. P., Chugunova E. A., Burilov A. R., Nenajdenko V. G., Sinyashin O. G. Synthesis and structure of nitro-substituted phosphacoumarins // Mendeleev Communications. 2026.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.71267/mencom.8136
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8136
TI - Synthesis and structure of nitro-substituted phosphacoumarins
T2 - Mendeleev Communications
AU - Zalaltdinova, A. V.
AU - Volodina, Yu. M.
AU - Gazizov, A. S.
AU - Gerasimova, D. P.
AU - Chugunova, E. A.
AU - Burilov, A. R.
AU - Nenajdenko, V. G.
AU - Sinyashin, O. G.
PY - 2026
DA - 2026/11/05
PB - Mendeleev Communications
ER -
BibTex
Cite this
BibTex (up to 50 authors)
Copy cite
@article{2026_Zalaltdinova,
author = {A. V. Zalaltdinova and Yu. M. Volodina and A. S. Gazizov and D. P. Gerasimova and E. A. Chugunova and A. R. Burilov and V. G. Nenajdenko and O. G. Sinyashin},
title = {Synthesis and structure of nitro-substituted phosphacoumarins},
journal = {Mendeleev Communications},
year = {2026},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8136},
doi = {10.71267/mencom.8136}
}
Views / Visits / Downloads
61 / 57 / 12

Keywords

coordination polymers
coumarins
nitro compounds
organophosphorus compounds
phosphacoumarins
phosphonates

Abstract

The reaction of 3-bromo-2-hydroxy-2-phosphacoumarin 2-oxides with sodium nitrite proceeds as the replacement of bromine atom by the nitro group, which affords the corresponding 3-nitro derivatives as sodium salts. X-ray diffraction study for the two representatives demonstrates that their structures can be classified as coordination polymers.

Funders

Russian Science Foundation
25-73-20015

References

2.
Photoexcited nitroarenes for the oxidative cleavage of alkenes
Ruffoni A., Hampton C., Simonetti M., Leonori D.
Nature , 2022
3.
Photoinduced Oxygen Transfer Using Nitroarenes for the Anaerobic Cleavage of Alkenes
Wise D.E., Gogarnoiu E.S., Duke A.D., Paolillo J.M., Vacala T.L., Hussain W.A., Parasram M.
Journal of the American Chemical Society , 2022
4.
A General Strategy to Access Pharmaceutically Relevant Pyridines from Nitroarenes
Saha A., Pan A., Ghosh D., Pal A., Guin S., Redhu A.K., Gota V., Maiti D.
Angewandte Chemie - International Edition , 2025
5.
Continuous Flow Synthesis of tert-Butyl Nitrite and Its Applications as Nitrating Agent
Mittal A.K., Prakash G., Pathak P., Dutta B., Ahalyan N., Maiti S., Maiti D.
Organic Process Research and Development , 2023
6.
Secondary Amines as Lewis Bases in Nitroalkene Activation
Yan W., Shi X., Zhong C.
Asian Journal of Organic Chemistry , 2013
7.
Halimehjani A.Z., Namboothiri I.N., Hooshmand S.E.
RSC Advances , 2014
8.
Song L., Fan Z., Zhang A.
Organic and Biomolecular Chemistry , 2019
9.
Synthetic Protocols for Aromatic Nitration: A Review
Patel S.S., Patel D.B., Patel H.D.
ChemistrySelect , 2021
10.
Recent progress in the nitration of arenes and alkenes
Qian Y., Zheng L., Xiang H., Yang H.
Organic and Biomolecular Chemistry , 2021
11.
Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity
Lecomte H., Fernandes A.J., Katayev D.
Angewandte Chemie - International Edition , 2026
12.
Recent advances in nitro-involved radical reactions
Huang J., Ding F., Rojsitthisak P., He F., Wu J.
Organic Chemistry Frontiers , 2020
13.
Recent Advances in the Nitration of Olefins
Paul N., Maity S., Panja S., Maiti D.
Chemical Record , 2021
14.
Recent Advancements on Nitration of Anilines Utilizing Diverse Nitrating Agents
Iqbal Z., Joshi A., Singh S., Rai P., De S.R.
Synthesis , 2025
15.
Nitro-Group-Containing Drugs
Nepali K., Lee H., Liou J.
Journal of Medicinal Chemistry , 2018
18.
Korotaev V.Y., Kutyashev I.B., Barkov A.Y., Sosnovskikh V.Y.
Russian Chemical Reviews , 2019
19.
Synthesis, in vitro cytotoxicity and apoptosis inducing study of 2-aryl-3-nitro-2H-chromene derivatives as potent anti-breast cancer agents
Rahmani-Nezhad S., Safavi M., Pordeli M., Ardestani S.K., Khosravani L., Pourshojaei Y., Mahdavi M., Emami S., Foroumadi A., Shafiee A.
European Journal of Medicinal Chemistry , 2014
20.
Advances in the Chemical Transformations Involving Nitroalkenes Embedded in Heterocyclic Framework
Kumar A., Kumar M., 1 M., Kumar S., Gupta A., Sharma S., Singh P.
Asian Journal of Organic Chemistry , 2025
21.
Li B., Zhou B., Lu H., Ma L., Peng A.
European Journal of Medicinal Chemistry , 2010
22.
Mina Hariri, Fatemeh Darvish, Karen-Pacelye Mengue Me Ndong, Rachida Babouri, Rachida Babouri, Gabin Mwande-Maguene, Alexander R Burilov, Patricia Licznar-Fajardo, Jean-Luc Pirat, Tahar Ayad, David Virieux
GSC Biological and Pharmaceutical Sciences , 2021
23.
Sennikova V.V., Zalaltdinova A.V., Sadykova Y.M., Khamatgalimov A.R., Gazizov A.S., Voloshina A.D., Lyubina A.P., Amerhanova S.K., Voronina J.K., Chugunova E.A., Appazov N.O., Burilov A.R., Pudovik M.A.
International Journal of Molecular Sciences , 2022
25.
Zalaltdinova Alena Vladimirovna, Appazov Nurbol Orynbasaruly, Sadykova Yulia Maskhutovna, Gazizov Almir Sabirovich, Akylbekov Nurgali Ikramovich, Darmagambet Klara Khayrolla kyzy, Turmanov Rakhymzhan Akhmetkhanovich, Syakaev Victor Vasil'evich, Gerasimova Daria Pavlovna, Chugunova Elena Alexandrovna, Burilov Alexander Romanovich, Sinyashin Oleg Gerol'dovich
Mendeleev Communications , 2025
26.
Synthesis and Structure of Novel Bromine-Containing Derivatives of 2-Hydroxybenzo[e][1,2]oxaphosphinine 2-Oxides
Matveeva V.I., Zalaltdinova A.V., Sadykova Y.M., Smailov A.K., Bakhtiozina L.R., Gerasimova D.P., Syakaev V.V., Gazizov A.S., Burilov A.R.
Russian Journal of General Chemistry , 2025
27.
Unexpectedly High Acidity of Water-Soluble Phosphacoumarins
Ivanenko T.Y., Zalaltdinova A.V., Darmagambet K.K., Gerasimova M.A., Sadykova Y.M., Levandovski V.D., Gazizov A.S., Akylbekov N.I., Appazov N.O., Burilov A.R., Lutoshkin M.A.
Chemistry , 2025
28.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D.
Journal of Applied Crystallography , 2015
29.
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances , 2015
30.
Sheldrick G.M.
Acta crystallographica. Section C, Structural chemistry , 2015
31.
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography , 2009
32.
Macrae C.F., Sovago I., Cottrell S.J., Galek P.T., McCabe P., Pidcock E., Platings M., Shields G.P., Stevens J.S., Towler M., Wood P.A.
Journal of Applied Crystallography , 2020