Home / Publications / Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis

Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis

, 
Alexandra S. Vishnevich 2
Alexandra S. Vishnevich
,  , 
Galina N. Baeva 1
Galina N. Baeva
, 
Dmitry P. Melnikov 2
Dmitry P. Melnikov
,  , 
10.71267/mencom.8060
Published 2026-06-03 , received 2026-04-08
Communication , Volume 36, Issue 5
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Rassolov A. V. et al. Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis // Mendeleev Communications. 2026. Vol. 36. No. 5.
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Rassolov A. V., Vishnevich A. S., Patil E. D., Baeva G. N., Melnikov D. P., Bokarev D. A., Stakheev A. Y. Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis // Mendeleev Communications. 2026. Vol. 36. No. 5.
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TY - JOUR
DO - 10.71267/mencom.8060
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8060
TI - Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis
T2 - Mendeleev Communications
AU - Rassolov, Alexander V.
AU - Vishnevich, Alexandra S.
AU - Patil, Ekaterina D.
AU - Baeva, Galina N.
AU - Melnikov, Dmitry P.
AU - Bokarev, Dmitriy A.
AU - Stakheev, Alexander Yu.
PY - 2026
DA - 2026/06/03
PB - Mendeleev Communications
IS - 5
VL - 36
ER -
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Cite this
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@article{2026_Rassolov,
author = {Alexander V. Rassolov and Alexandra S. Vishnevich and Ekaterina D. Patil and Galina N. Baeva and Dmitry P. Melnikov and Dmitriy A. Bokarev and Alexander Yu. Stakheev},
title = {Effect of TiO2 textural characteristics on the performance of supported PdCu nanoparticles in two-stage olefin synthesis},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8060},
number = {5},
doi = {10.71267/mencom.8060}
}
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Keywords

bimetallic alloy
copper
nanoparticles
olefins
selective hydrogenation
Sonogashira cross-coupling
Tandem catalysis

Abstract

The influence of the porous structure and phase composition of the TiO2 support on the performance of heterogeneous bimetallic PdCu catalysts in the two-stage synthesis of cis- and trans-stilbenes was investigated. It was found that the combined effect of a developed porous structure and strong metal–support interactions has a positive effect on catalytic performance at each individual stage of the process.

Funders

Russian Science Foundation
25-73-00079

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