Keywords
CaWO4
DSC-TG
FTIR-spectra
hydroxyapatite
phase evolution
thermal stability
tungstate anions
Abstract
Materials based on hydroxyapatite containing tungstate anions were synthesized via precipitation and heat-treated up to 1200 °C. The incorporation of tungstate anions retards thermal decomposition and shifts the onset of CaO formation to higher temperatures compared with pure hydroxyapatite. The presence of CaWO4 in WO42–-enriched (6.0 mol%) powder resulted in the increased mass loss above 1200 °C, accompanied by the appearance of WO3.
Funders
Russian Science Foundation
22-79-10293-P
References
2.
Dorozhkin S.V.
Journal of Composites Science,
2024
3.
Kharissova O.V., Méndez Y.P., Kharisov B.I., González L.T., Dorozhkin S.V.
Particuology,
2025
4.
Ibrahim M., Labaki M., Giraudon J., Lamonier J.
Journal of Hazardous Materials,
2020
5.
Huixia L., Yong L., Yanni T., Lanlan L., Qing Z., Kun L., Hanchun T.
New Journal of Chemistry,
2015
6.
Petrakova N.V., Zobkova Y.O., Komlev V.S., Ashmarin A.A., Lysenkov A.S., Volchenkova V.A., Barinov S.M., Sadovnikova M.A., Murzakhanov F.F., Gafurov M.R., Kudryavtsev E.A., Kozyukhin S.A., Trigub A.L., Rogachev A.V.
Ceramics International,
2024
7.
Ooi C., Ling Y.P., Pung S., Yeoh F.
Powder Technology,
2019
8.
Goldberg M.A., Eseva E.A., Donskaya N.O., Fomin A.S., Antonova O.S., Leonov A.V., Konovalov A.A., Murzakhanov F.F., Kudriavtsev E.A., Akopyan A.V., Gafurov M.R., Barinov S.M., Komlev V.S.
Ceramics International,
2025
9.
Reynaud C., Thomas C., Brouri D., Millot Y., Miche A., Costentin G.
Catalysis Today,
2024
10.
Kareem R.O., Barzinjy A.A., Ates T., Bulut N., Keser S., Kaygili O.
Journal of the Australian Ceramic Society,
2025
11.
Kee C.C., Ismail H., Mohd Noor A.F.
Journal of Materials Science and Technology,
2013
12.
Golubchikov D.O., Safronova T.V., Podlyagin V.A., Shatalova T.B., Kolesnik I.V., Putlayev V.I.
Mendeleev Communications,
2024
13.
Medvecky L., Giretova M., Stulajterova R., Luptakova L., Sopcak T.
Materials,
2021
14.
Dhal J., Fielding G., Bose S., Bandyopadhyay A.
Journal of Biomedical Materials Research - Part B Applied Biomaterials,
2012
15.
Maiti M., Sarkar M., Liu D., Xu S., Maiti S., Paul B.K., Das S.
New Journal of Chemistry,
2018
16.
Silingardi F., Bonvicini F., Cassani M.C., Mazzaro R., Rubini K., Gentilomi G.A., Bigi A., Boanini E.
Journal of Functional Biomaterials,
2022
17.
Donskaya N.O., Goldberg M.A., Eseva E.A., Khayrutdinova D.R., Fomin A.S., Latypova S.S., Leonov A.V., Konovalov A.A., Utkin D.A., Sadovnikova M.A., Kaygili O., Bulut N., Gafurov M.R., Akopyan A.V., Komlev V.S., et. al.
Inorganic Chemistry Communication,
2026
18.
Domínguez M.I., Cojocaru B., Tudorache M., Odriozola J.A., Centeno M.A., Parvulescu V.I.
Comptes Rendus Chimie,
2016
19.
Vishwakarma R., Rathod V., Mannepalli L.K.
Journal of Chemical Sciences,
2022
20.
Crosman A., Gelbard G., Poncelet G., Parvulescu V.I.
Applied Catalysis A: General,
2004
21.
PREPARATION AND CHARACTERIZATION OF HYDROXYAPATITE BY A REACTION OF CALCIUM TUNGSTATE WITH PHOSPHATE
Kawakami M., Shimamura S., Moriyoshi Y., Monma H., Watanabe Y., Komatsu Y., Ishigaki T.
Phosphorus Research Bulletin,
2006
22.
Copper loaded hydroxyapatite catalyst for selective catalytic reduction of nitric oxide with ammonia
Tounsi H., Djemal S., Petitto C., Delahay G.
Applied Catalysis B: Environmental,
2011
23.
Jemli Y.E., Abdelouahdi K., Minh D.P., Barakat A., Solhy A.
2022
24.
Gu M., Li W., Jiang L., Li X.
Acta Biomaterialia,
2022
25.
Shkir M., Kilany M., Yahia I.S.
Ceramics International,
2017
26.
Duta L., Oktar F.N., Stan G.E., Popescu-Pelin G., Serban N., Luculescu C., Mihailescu I.N.
Applied Surface Science,
2013
27.
Terebilenko K.V., Chornii V.P., Zozulia V.O., Gural'skiy I.A., Shova S.G., Nedilko S.G., Slobodyanik M.S.
RSC Advances,
2022
28.
Thongtem T., Kungwankunakorn S., Kuntalue B., Phuruangrat A., Thongtem S.
Journal of Alloys and Compounds,
2010
29.
Xia M.J., Li R.K.
Solid State Communications,
2015
30.
Mikhaylov Georgy Sergeyevich, Gerasimova Irina I., Ratova Daria-Mariia V., Mikheev Ivan Vladimirovich, Klein Olga I., Chernysheva Maria Grigor'evna, Badun Gennadii Aleksandrovich
Mendeleev Communications,
2026
31.
Chaikina M.V., Bulina N.V., Prosanov I.Y., Gerasimov K.B., Makarova S.V.
Chemical Papers,
2023
32.
Nowicki D.A., Skakle J.M., Gibson I.R.
Journal of Solid State Chemistry,
2021
33.
Yin Y., Li Y., Liu S., Jiang Y., Liu X., Zhang P.
ACS Omega,
2024
34.
Tacker R.C., Rakovan J., Harlov D., Hughes J.M., Cichy S.B.
American Mineralogist,
2024
35.
BONEL G., HEUGHEBAERT J., HEUGHEBAERT M., LACOUT J.L., LEBUGLE A.
Annals of the New York Academy of Sciences,
1988
36.
Tamai M.
Journal of Materials Science: Materials in Medicine,
2003
37.
Berzina-Cimdina L., Borodajenko N.
2012
38.
Goldberg M.A., Protsenko P.V., Smirnov V.V., Antonova O.S., Smirnov S.V., Konovalov A.A., Vorckachev K.G., Kudryavtsev E.A., Barinov S.M., Komlev V.S.
Journal of Materials Research and Technology,
2020
39.
Kaygili O., Düşkün Y., Barzinjy A.A., Kareem R.O., Ates T., Keser S., Tatar B., Ali A.L., Bulut N., Ercan F., Ercan İ., İnce T.
Ceramics International,
2025
40.
Senyshyn A., Kraus H., Mikhailik V.B., Yakovyna V.
Physical Review B,
2004