Keywords
EPR
ionic liquids
metal–organic frameworks
porous liquids
spin probes
Abstract
Porous liquids (PLs) represent a relatively new type of fluid media promising for many applications. Their intrinsic heterogeneous structure on microscopic scale is the core of unusual physicochemical and functional properties of PLs. Although PLs emerged at the interface of other well-developed fields of chemistry and materials science, their unique properties welcome the development of new specific experimental approaches to characterize structure and functions of PLs, as well as their stability. In this focus article we briefly overview major current trends in the design and development of PLs and discuss relevant methods of their investigation, with a particular emphasis on recent applications of Electron Paramagnetic Resonance (EPR) spectroscopy in this emerging field.
Funders
Russian Science Foundation
24-13-00119
References
1.
Giri N., Del Pópolo M.G., Melaugh G., Greenaway R.L., Rätzke K., Koschine T., Pison L., Gomes M.F., Cooper A.I., James S.L.
Nature,
2015
2.
3.
Bavykina A., Cadiau A., Gascon J.
Coordination Chemistry Reviews,
2019
4.
5.
6.
Jie K., Zhou Y., Ryan H.P., Dai S., Nitschke J.R.
Advanced Materials,
2021
7.
Ahmad M.Z., Fuoco A.
Current Research in Green and Sustainable Chemistry,
2021
8.
Bennett T.D., Coudert F., James S.L., Cooper A.I.
Nature Materials,
2021
9.
Wang D., Xin Y., Yao D., Li X., Ning H., Zhang H., Wang Y., Ju X., He Z., Yang Z., Fan W., Li P., Zheng Y.
Advanced Functional Materials,
2021
10.
Lee A.F., Wilson K.
Chem,
2022
11.
Rimsza J.M., Nenoff T.M.
ACS applied materials & interfaces,
2022
12.
Egleston B.D., Mroz A., Jelfs K.E., Greenaway R.L.
Chemical Science,
2022
13.
Mokhtarinori N., Yang Z., Dai S.
Current Opinion in Green and Sustainable Chemistry,
2022
14.
Mahdavi H., Smith S.J., Mulet X., Hill M.R.
Materials Horizons,
2022
15.
Yin J., Zhang J., Fu W., Ran H., Zhang Y., Zhang M., Jiang W., Li H., Zhu W., Li H.
Separation and Purification Technology,
2022
16.
Fan W., Xin Y., Yang R., Li P., Qian L., Lu Y., Yao D., Zheng Y., Wang D.
ACS Applied Energy Materials,
2025
17.
Sheng L., Ning H., Wang Y., Li C., Huang S., Zhang Y., Xu B., Chen Z.
Green Chemistry,
2025
18.
Liu R., Zhang C., Chi C., Zhao S., Tang C., Zhu B., Qiao K., Yu J.
ACS applied materials & interfaces,
2025
19.
Zhu M.
Inorganic Chemistry Frontiers,
2025
20.
Jin D., Qi D., Zhang M., Zhou Z., Ren Z.
Separation and Purification Technology,
2025
21.
Li W., Mukherjee S.
National Science Review,
2025
22.
Liu S., Meng L., Zhang J., Xin Y., Dong Z., Qian L., Xiang B., Zhang J., Miao Y., Ren Z., Fan W., Fan J., Zhou W., Wang D.
ChemistrySelect,
2026
23.
Dai D., Luo L., Zhu Q., Wang D., Li T.
Angewandte Chemie - International Edition,
2023
24.
Brand M.C., Rankin N., Cooper A.I., Greenaway R.L.
Chemistry - A European Journal,
2022
25.
Weng P., Liu K., Yuan M., Huang G., Wu K., Yang X., Dai H., Lu W., Li D.
Small,
2023
26.
Xu Y., Ren Y., Liu X., Li H., Lu Z.
Wuli Huaxue Xuebao/ Acta Physico - Chimica Sinica,
2024
27.
Lai B., Crawford D.E., Wu H., James S.L.
Angewandte Chemie - International Edition,
2024
28.
Yu H., Liu M., Zhang G., Wang F.
Chemical Engineering Journal,
2024
29.
Li E., Ganesan A., Qiu L., Liu H., Ivanov A.S., He L., Nalaoh P., Jenkins D.M., Wang T., Kim E., Jiang D., Mahurin S.M., Yang Z., Dai S.
Advanced Functional Materials,
2024
30.
Liu Y., Jin H., Li M., Zuo M., Dinker M.K., Kou J., Yan J., Ding L., Sun L.
Angewandte Chemie - International Edition,
2025
31.
Zhou X., Ji L., Liu K., Gao F., Ren Z., Zhou Z.
Chemical Engineering Science,
2025
32.
Mroz A.M., Egleston B.D., Sherwood J., Morel R.C., Jelfs K.E., Greenaway R.L.
Chemical Science,
2025
33.
Zhang J., Chai S., Qiao Z., Mahurin S.M., Chen J., Fang Y., Wan S., Nelson K., Zhang P., Dai S.
Angewandte Chemie - International Edition,
2014
34.
Zhang Z., Yang B., Zhang B., Cui M., Tang J., Qiao X.
Nature Communications,
2022
35.
Melaugh G., Giri N., Davidson C.E., James S.L., Del Pópolo M.G.
Physical Chemistry Chemical Physics,
2014
36.
Knebel A., Bavykina A., Datta S.J., Sundermann L., Garzon-Tovar L., Lebedev Y., Durini S., Ahmad R., Kozlov S.M., Shterk G., Karunakaran M., Carja I.D., Simic D., Weilert I., Klüppel M., et. al.
Nature Materials,
2020
37.
Ben Ghozi-Bouvrande J., Pellet-Rostaing S., Dourdain S.
Nanomaterials,
2021
38.
Giri N., Davidson C.E., Melaugh G., Del Pópolo M.G., Jones J.T., Hasell T., Cooper A.I., Horton P.N., Hursthouse M.B., James S.L.
Chemical Science,
2012
39.
Costa Gomes M., Pison L., Červinka C., Padua A.
Angewandte Chemie - International Edition,
2018
40.
He C., Zou Y., Si D., Chen Z., Liu T., Cao R., Huang Y.
Nature Communications,
2023
41.
Du S., Huang J., Ryder M.R., Daemen L.L., Yang C., Zhang H., Yin P., Lai Y., Xiao J., Dai S., Chen B.
Nature Communications,
2023
42.
Huang D., Dong Y., Guo H., Yang E., Chen Y., Luo M., Pan Z., Liu J., Li L., Zhang H., Ye B.
Macromolecules,
2023
43.
Mow R.E., Lipton A.S., Shulda S., Gaulding E.A., Gennett T., Braunecker W.A.
Journal of Materials Chemistry A,
2020
44.
Greenaway R.L., Holden D., Eden E.G., Stephenson A., Yong C.W., Bennison M.J., Hasell T., Briggs M.E., James S.L., Cooper A.I.
Chemical Science,
2017
45.
Egleston B.D., Luzyanin K.V., Brand M.C., Clowes R., Briggs M.E., Greenaway R.L., Cooper A.I.
Angewandte Chemie - International Edition,
2020
46.
Lepre L.F., Szala-Bilnik J., Pison L., Traïkia M., Pádua A.A., Ando R.A., Costa Gomes M.F.
Physical Chemistry Chemical Physics,
2017
47.
Gulyaev S.A., Bakulina O.D., Poryvaev A.S., Yazikova A.A., Smirnova K.A., Prikhod'ko S.A., Sagdeev R.Z., Adonin N.Y., Fedin M.V.
Journal of Molecular Liquids,
2025
48.
Bagryanskaya E.G., Krumkacheva O.A., Fedin M.V., Marque S.R.
Methods in Enzymology,
2015
49.
50.
Krumkacheva O.A., Timofeev I.O., Politanskaya L.V., Polienko Y.F., Tretyakov E.V., Rogozhnikova O.Y., Trukhin D.V., Tormyshev V.M., Chubarov A.S., Bagryanskaya E.G., Fedin M.V.
Angewandte Chemie - International Edition,
2019
51.
Wort J.L., Ackermann K., Giannoulis A., Stewart A.J., Norman D.G., Bode B.E.
Angewandte Chemie - International Edition,
2019
52.
Wort J.L., Arya S., Ackermann K., Stewart A.J., Bode B.E.
Journal of Physical Chemistry Letters,
2021
53.
Timofeev I.O., Politanskaya L.V., Tretyakov E.V., Polienko Y.F., Tormyshev V.M., Bagryanskaya E.G., Krumkacheva O.A., Fedin M.V.
Physical Chemistry Chemical Physics,
2022
54.
Polyukhov D.M., Poryvaev A.S., Gromilov S.A., Fedin M.V.
Nano Letters,
2019
55.
Poryvaev A.S., Polyukhov D.M., Fedin M.V.
ACS applied materials & interfaces,
2020
56.
Poryvaev A.S., Yazikova A.A., Polyukhov D.M., Chinak O.A., Richter V.A., Krumkacheva O.A., Fedin M.V.
Journal of Physical Chemistry C,
2021
57.
Poryvaev A.S., Yazikova A.A., Polyukhov D.M., Fedin M.V.
Microporous and Mesoporous Materials,
2022
58.
Efremov A.A., Poryvaev A.S., Polyukhov D.M., Fedin M.V.
Microporous and Mesoporous Materials,
2022
59.
Spitsyna A.S., Poryvaev A.S., Sannikova N.E., Yazikova A.A., Kirilyuk I.A., Dobrynin S.A., Chinak O.A., Fedin M.V., Krumkacheva O.A.
Molecules,
2022
60.
Poryvaev A., Larionov K., Albrekht Y., Efremov A.A., Kiryutin A.S., Smirnova K., Evtushok V.Y., Fedin M.V.
Physical Chemistry Chemical Physics,
2023
61.
Poryvaev A., Efremov A.A., Alimov D., Smirnova K., Polyukhov D., Sagdeev R., Jacoutot S., Marque S.R., Fedin M.V.
Chemical Science,
2024
62.
Yazikova A.A., Tomilov A.S., Livanovich K.S., Smirnova K.A., Kirilyuk I.A., Polienko Y.F., Poryvaev A.S., Fedin M.V.
Journal of Physical Chemistry C,
2025
63.
Efremov A.A., Zhitkeyev R., Livanovich K.S., Poryvaev A.S., Fedin M.V.
Analytical Chemistry,
2025
64.
Ivanov M.Y., Veber S.L., Prikhod’ko S.A., Adonin N.Y., Bagryanskaya E.G., Fedin M.V.
Journal of Physical Chemistry B,
2015
65.
Ivanov M.Y., Prikhod’ko S.A., Adonin N.Y., Kirilyuk I.A., Adichtchev S.V., Surovtsev N.V., Dzuba S.A., Fedin M.V.
Journal of Physical Chemistry Letters,
2018
66.
Ivanov M.Y., Fedin M.V.
Mendeleev Communications,
2018
67.
Bakulina O.D., Ivanov M.Y., Prikhod'ko S.A., Pylaeva S., Zaytseva I.V., Surovtsev N.V., Adonin N.Y., Fedin M.V.
Nanoscale,
2020
68.
Ivanov M.Y., Poryvaev A.S., Polyukhov D.M., Prikhod'ko S.A., Adonin N.Y., Fedin M.V.
Nanoscale,
2020
69.
Ivanov M.Y., Surovtsev N.V., Fedin M.V.
Russian Chemical Reviews,
2022
70.
Yu. Ivanov M., Bakulina O.D., Polienko Y.F., Kirilyuk I.A., Prikhod'ko S.A., Yu. Adonin N., Fedin M.V.
Journal of Molecular Liquids,
2023
71.
Park K.S., Ni Z., Côté A.P., Choi J.Y., Huang R., Uribe-Romo F.J., Chae H.K., O’Keeffe M., Yaghi O.M.
Proceedings of the National Academy of Sciences of the United States of America,
2006
73.
Calle C., Sreekanth A., Fedin M., Forrer J., Garcia-Rubio I., Gromov I., Hinderberger D., Kasumaj B., Léger P., Mancosu B., Mitrikas G., Santangelo M., Stoll S., Schweiger A., Tschaggelar R., et. al.
Helvetica Chimica Acta,
2006
74.
![H, D and HD adsorption upon the metal-organic framework [CuZn(btc)] studied by pulsed ENDOR and HYSCORE spectroscopy](https://mendcomm.colab.ws/storage/images/resized/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_small_thumb.webp)
Jee B., Hartmann M., Pöppl A.
Molecular Physics,
2013
75.
Jee B., St. Petkov P., Vayssilov G.N., Heine T., Hartmann M., Pöppl A.
Journal of Physical Chemistry C,
2013
76.
Šimėnas M., Jee B., Hartmann M., Banys J., Pöppl A.
Journal of Physical Chemistry C,
2015
77.
ref-10.71267-mendc7475-1-78-1-0
Dokl. Chem.,
2026
78.
Zhang H., Tan J., Liu X., Zhou C., Luan C., Zhang H., Li L., Zhou X.
Advanced Materials,
2025