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Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4]

Anna Nikolaevna Semerikova 1
Anna Nikolaevna Semerikova
, 
Nata Ivanovna Matskevich 1
Nata Ivanovna Matskevich
, 
Anton V Klimenko 1, 2
Anton V Klimenko
, 
Aleksandr I Aparnev 2
Aleksandr I Aparnev
, 
Valerii P Zaitsev 3
Valerii P Zaitsev
, 
Mariya Yuryevna Rozhina 1
Mariya Yuryevna Rozhina
, 
Evgeniy Nikolaevich Tkachev 1
Evgeniy Nikolaevich Tkachev
2 Novosibirsk State Technical University, 630073 Novosibirsk, Russian Federation
3 Siberian State University of Water Transport, 630033 Novosibirsk, Russian Federation
10.71267/mencom.8023
Published 28 July 2026 , received 24 February 2026
Communication , Volume 36, Issue 5, 607-609
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Semerikova A. N. et al. Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4] // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 607-609.
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Semerikova A. N., Matskevich N. I., Klimenko A. V., Aparnev A. I., Zaitsev V. P., Rozhina M. Y., Tkachev E. N. Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4] // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 607-609.
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TY - JOUR
DO - 10.71267/mencom.8023
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8023
TI - Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4]
T2 - Mendeleev Communications
AU - Semerikova, Anna Nikolaevna
AU - Matskevich, Nata Ivanovna
AU - Klimenko, Anton V
AU - Aparnev, Aleksandr I
AU - Zaitsev, Valerii P
AU - Rozhina, Mariya Yuryevna
AU - Tkachev, Evgeniy Nikolaevich
PY - 2026
DA - 2026/07/28
PB - Mendeleev Communications
SP - 607-609
IS - 5
VL - 36
ER -
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@article{2026_Semerikova,
author = {Anna Nikolaevna Semerikova and Nata Ivanovna Matskevich and Anton V Klimenko and Aleksandr I Aparnev and Valerii P Zaitsev and Mariya Yuryevna Rozhina and Evgeniy Nikolaevich Tkachev},
title = {Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4]},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8023},
number = {5},
pages = {607--609},
doi = {10.71267/mencom.8023}
}
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Semerikova, Anna Nikolaevna, et al. “Enthalpy of formation and lattice enthalpy of neodymium potassium molybdate [K5Nd(MoO4)4].” Mendeleev Communications, vol. 36, no. 5, Jul. 2026, pp. 607-609. https://mendcomm.colab.ws/publications/10.71267/mencom.8023.
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Keywords

enthalpy of formation
lattice enthalpy
potassium neodymium molybdate
solid-state synthesis
solution calorimetry
stabilization energy

Abstract

The compound K5Nd(MoO4)4, which holds promise for laser applications, was prepared using solid-phase synthesis. Its formation enthalpy, stabilization energy and lattice enthalpy were determined. The absolute value of the lattice enthalpy was shown to increase upon going from K5Nd(MoO4)4 to K5Gd(MoO4)4, which correlates with a decrease in the rare earth element’s radius and an increase in the luminescence wavelength when replacing Nd with Gd.

Funders

Ministry of Education and Science of the Russian Federation
FWUZ-2025-0004

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