Home / Articles / Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene

Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene

Eugenia Mikhailovna Kholodkova 1
Eugenia Mikhailovna Kholodkova
, 
Maria M Belova 1
Maria M Belova
, 
Alexandr Vladimirovich Ponomarev 1
Alexandr Vladimirovich Ponomarev
10.71267/mencom.8017
Published 28 July 2026 , received 11 February 2026
Communication , Volume 36, Issue 5, 525-527
0
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Kholodkova E. M., Belova M. M., Ponomarev A. V. Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 525-527.
GOST all authors (up to 50)
Copy cite
Kholodkova E. M., Belova M. M., Ponomarev A. V. Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 525-527.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.71267/mencom.8017
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8017
TI - Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene
T2 - Mendeleev Communications
AU - Kholodkova, Eugenia Mikhailovna
AU - Belova, Maria M
AU - Ponomarev, Alexandr Vladimirovich
PY - 2026
DA - 2026/07/28
PB - Mendeleev Communications
SP - 525-527
IS - 5
VL - 36
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{2026_Kholodkova,
author = {Eugenia Mikhailovna Kholodkova and Maria M Belova and Alexandr Vladimirovich Ponomarev},
title = {Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8017},
number = {5},
pages = {525--527},
doi = {10.71267/mencom.8017}
}
MLA
Cite this
MLA
Copy cite
Kholodkova, Eugenia Mikhailovna, et al. “Radiolytic redistribution of functional groups in 1-nitro-3-(trifluoromethyl)benzene.” Mendeleev Communications, vol. 36, no. 5, Jul. 2026, pp. 525-527. https://mendcomm.colab.ws/publications/10.71267/mencom.8017.
Views / Visits
113 / 113

Keywords

defluorination
denitration
nitration
organofluorine compounds
phenols
radiolysis

Abstract

Radiolysis of deaerated 1-nitro-3-(trifluoromethyl)benzene leads to mononuclear (predominantly) and binuclear arenes in which the nitro groups are replaced by NO or OH ones. The conversion of the nitro group to NO is caused by the action of the radiation-induced reducing intermediates. In parallel, the formed oxygen radical anions, atomic oxygen and OH radicals participate in the hydroxylation of the original molecules and radiolysis semi-products.

Funders

Russian Academy of Sciences
122011300061-3

References

1.
Solvent Extraction Systems for Separation of An(III) and Ln(III): Overview of Static and Dynamic Tests
Evsiunina M.V., Matveev P.I., Kalmykov S.N., Petrov V.G.
Moscow University Chemistry Bulletin, 2021
3.
Single- and Two-Electron Reduction of Nitroaromatic Compounds by Flavoenzymes: Mechanisms and Implications for Cytotoxicity
Čėnas N., Nemeikaitė-Čėnienė A., Kosychova L.
International Journal of Molecular Sciences, 2021
4.
Redox potentials of trifluoromethyl-containing compounds
Jiang Y., Yu H., Fu Y., Liu L.
Science China Chemistry, 2014
5.
Kinetic study of the oxidation of phenolic derivatives of α,α,α-trifluorotoluene by singlet molecular oxygen [O2(1Δg)] and hydrogen phosphate radicals
Rosso J.A., Criado S., Bertolotti S.G., Allegretti P.E., Furlong J., García N.A., Gonzalez M.C., Mártire D.O.
Photochemical and Photobiological Sciences, 2003
6.
A unified flow strategy for the preparation and use of trifluoromethyl-heteroatom anions
Spennacchio M., Bernús M., Stanić J., Mazzarella D., Colella M., Douglas J.J., Boutureira O., Noël T.
Science, 2024
7.
Radiation-induced Degradation of Nitrobenzene in Aqueous Solutions
Feng S., Zhang S., Yu H., Li Q.
Chemistry Letters, 2003
8.
Knight J.A.
Radiation Research, 1972
9.
Kinetics and Mechanisms of Radiolytic Degradation of Nitrobenzene in Aqueous Solutions
Zhang S., Jiang H., Li M., Yu H., Yin H., Li Q.
Environmental Science & Technology, 2007
10.
Determination of the Rate Constant of the Reaction of Benzene with Atomic Fluorine by the Method of Competing Reactions
Vasiliev E.S., Volkov N.D., Karpov G.V., Morozov I.I., Nigmatullin D.R., Saigina E.A., Savilov S.V., Umanskii S.Y., Butkovskaya N.I.
Russian Journal of Physical Chemistry B, 2021
11.
Rate Constants for Abstraction of H from the Fluoromethanes by H, O, F, and OH
Burgess D.R., Manion J.A.
Journal of Physical and Chemical Reference Data, 2021
13.
Ponomarev A.V., Bludenko A.V., Makarov I.E.
Mendeleev Communications, 2002
14.
Zhestkova T.P., Zhukova T.N., Ponomarev A.V., Tananaev I.G.
Mendeleev Communications, 2008
16.
Uchkina Daria Aleksandrovna, Ponomarev Alexandr Vladimirovich
Mendeleev Communications, 2023