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Top-down pulsed electrosynthesis of vanadium oxide bronzes

Anna Aleksandrovna Ulyankina 1
Anna Aleksandrovna Ulyankina
, 
Tatyana A Belichenko 1
Tatyana A Belichenko
, 
Mikhail Vladimirovich Gorshenkov 2
Mikhail Vladimirovich Gorshenkov
, 
Nikita Andreevich Faddeev 1
Nikita Andreevich Faddeev
, 
Vasily V Kaichev 3
Vasily V Kaichev
, 
Nina Vladimirovna Smirnova 1
Nina Vladimirovna Smirnova
1 Research Institute of Nanotechnology and New Materials, Platov South-Russian State Polytechnic University, 346428 Novocherkassk, Russian Federation
2 National University of Science and Technology ‘MISIS’, 119049 Moscow, Russian Federation
3 Federal Research Center G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
10.71267/mencom.8013
Published 28 July 2026 , received 4 February 2026
Communication , Volume 36, Issue 5, 604-606
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Ulyankina A. A. et al. Top-down pulsed electrosynthesis of vanadium oxide bronzes // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 604-606.
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Ulyankina A. A., Belichenko T. A., Gorshenkov M. V., Faddeev N. A., Kaichev V. V., Smirnova N. V. Top-down pulsed electrosynthesis of vanadium oxide bronzes // Mendeleev Communications. 2026. Vol. 36. No. 5. pp. 604-606.
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TY - JOUR
DO - 10.71267/mencom.8013
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.8013
TI - Top-down pulsed electrosynthesis of vanadium oxide bronzes
T2 - Mendeleev Communications
AU - Ulyankina, Anna Aleksandrovna
AU - Belichenko, Tatyana A
AU - Gorshenkov, Mikhail Vladimirovich
AU - Faddeev, Nikita Andreevich
AU - Kaichev, Vasily V
AU - Smirnova, Nina Vladimirovna
PY - 2026
DA - 2026/07/28
PB - Mendeleev Communications
SP - 604-606
IS - 5
VL - 36
ER -
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@article{2026_Ulyankina,
author = {Anna Aleksandrovna Ulyankina and Tatyana A Belichenko and Mikhail Vladimirovich Gorshenkov and Nikita Andreevich Faddeev and Vasily V Kaichev and Nina Vladimirovna Smirnova},
title = {Top-down pulsed electrosynthesis of vanadium oxide bronzes},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.8013},
number = {5},
pages = {604--606},
doi = {10.71267/mencom.8013}
}
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Ulyankina, Anna Aleksandrovna, et al. “Top-down pulsed electrosynthesis of vanadium oxide bronzes.” Mendeleev Communications, vol. 36, no. 5, Jul. 2026, pp. 604-606. https://mendcomm.colab.ws/publications/10.71267/mencom.8013.
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Keywords

electrochemical synthesis
pulsed alternating current
vanadium
vanadium oxide bronzes

Abstract

A top-down pulsed electrosynthesis was elaborated for layered vanadium oxide bronzes (MxVyOz) using bulk vanadium in NH4+, K+, and Na+-containing chloride electrolytes. The polarity reversal is essential for ensuring dissolution–in situ precipitation of MxVyOz, offering a sustainable route for upcycling vanadium into multifunctional materials.

Funders

Russian Science Foundation
23-79-10219

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