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Synthesis of pentacarbonyl molybdenum complexes of 3-substituted 1H-phospholane oxides

Tat'yana Viktorovna Tyumkina 1
Tat'yana Viktorovna Tyumkina
, 
Alevtina L Makhamatkhanova 1
Alevtina L Makhamatkhanova
, 
Ekaterina Yu Bulykina 1
Ekaterina Yu Bulykina
, 
Denis Nasimovich Islamov 1
Denis Nasimovich Islamov
10.71267/mencom.7977
Published 23 September 2026
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Tyumkina T. V. et al. Synthesis of pentacarbonyl molybdenum complexes of 3-substituted 1H-phospholane oxides // Mendeleev Communications. 2026.
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Tyumkina T. V., Makhamatkhanova A. L., Bulykina E. Yu., Islamov D. N. Synthesis of pentacarbonyl molybdenum complexes of 3-substituted 1H-phospholane oxides // Mendeleev Communications. 2026.
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TY - JOUR
DO - 10.71267/mencom.7977
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7977
TI - Synthesis of pentacarbonyl molybdenum complexes of 3-substituted 1H-phospholane oxides
T2 - Mendeleev Communications
AU - Tyumkina, Tat'yana Viktorovna
AU - Makhamatkhanova, Alevtina L
AU - Bulykina, Ekaterina Yu
AU - Islamov, Denis Nasimovich
PY - 2026
DA - 2026/09/23
PB - Mendeleev Communications
ER -
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@article{2026_Tyumkina,
author = {Tat'yana Viktorovna Tyumkina and Alevtina L Makhamatkhanova and Ekaterina Yu Bulykina and Denis Nasimovich Islamov},
title = {Synthesis of pentacarbonyl molybdenum complexes of 3-substituted 1H-phospholane oxides},
journal = {Mendeleev Communications},
year = {2026},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7977},
doi = {10.71267/mencom.7977}
}
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Keywords

1H-phospholane oxides
carbonyl complexes
conformational analysis
DFT calculation
molybdenum complexes
organophosphorus compounds
secondary phosphine oxides

Abstract

P-Coordinated pentacarbonyl molybdenum complexes based on cyclic secondary phosphine oxides have been synthesized by the thermal reaction of Mo(CO)6 with 3-substituted 1H-phospholane oxides in tetrahydrofuran. The structure and conformation of the synthesized complexes have been established using IR and multinuclear (1H, 13C, 31P, 95Mo) NMR spectroscopy, and simulated by DFT calculations.

Funders

Russian Science Foundation
24-23-00587

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