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Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols

Pavel A Konkin 1
Pavel A Konkin
, 
Nuri Mamedeevich Chobanov 1
Nuri Mamedeevich Chobanov
, 
Andrey Sergeevich Dmitrenok 1
Andrey Sergeevich Dmitrenok
,  ,  , 
Vladimir Anatol'evich D'yakonov 1
Vladimir Anatol'evich D'yakonov
10.71267/mencom.7961
Published 2026-03-24
Communication , Volume 36, Issue 3, 285-287
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Konkin P. A. et al. Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 285-287.
GOST all authors (up to 50) Copy
Konkin P. A., Chobanov N. M., Dmitrenok A. S., Ramazanov I. R., Dzhemilev U. M., D'yakonov V. A. Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 285-287.
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TY - JOUR
DO - 10.71267/mencom.7961
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7961
TI - Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols
T2 - Mendeleev Communications
AU - Konkin, Pavel A
AU - Chobanov, Nuri Mamedeevich
AU - Dmitrenok, Andrey Sergeevich
AU - Ramazanov, Ilfir Rifovich
AU - Dzhemilev, Usein Memetovich
AU - D'yakonov, Vladimir Anatol'evich
PY - 2026
DA - 2026/03/24
PB - Mendeleev Communications
SP - 285-287
IS - 3
VL - 36
ER -
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@article{2026_Konkin,
author = {Pavel A Konkin and Nuri Mamedeevich Chobanov and Andrey Sergeevich Dmitrenok and Ilfir Rifovich Ramazanov and Usein Memetovich Dzhemilev and Vladimir Anatol'evich D'yakonov},
title = {Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7961},
number = {3},
pages = {285--287},
doi = {10.71267/mencom.7961}
}
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Konkin, Pavel A., et al. “Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols.” Mendeleev Communications, vol. 36, no. 3, Mar. 2026, pp. 285-287. https://mendcomm.colab.ws/publications/10.71267/mencom.7961.
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Keywords

aluminacyclopentane
cycloalumination
cyclopentanol
triethylaluminum
zirconium dichloride
γ-butyrolactone

Abstract

The reaction between γ-butyrolactone and 3-alkyl-1-ethylaluminacyclopentanes (formed in situ through the Zr-catalyzed cycloalumination of α-olefins with Et3Al) affords 3-alkyl-1-(3-hydroxypropyl)cyclopentanols in yields of 65--70%.

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