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Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety

Ilya P. Limarev 1, 2
Ilya P. Limarev
, 
Ekaterina G Lebed 1
Ekaterina G Lebed
, 
Anna Vladimirovna Vologzhanina 1
Anna Vladimirovna Vologzhanina
, 
Margarita Gennad'evna Bugaenko 1
Margarita Gennad'evna Bugaenko
, 
Yan Zigfridovich Voloshin 1, 2
Yan Zigfridovich Voloshin
10.71267/mencom.7958
Published 2026-03-24
Communication , Volume 36, Issue 3, 282-284
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Limarev I. P. et al. Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 282-284.
GOST all authors (up to 50) Copy
Limarev I. P., Lebed E. G., Vologzhanina A. V., Bugaenko M. G., Voloshin Y. Z. Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 282-284.
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TY - JOUR
DO - 10.71267/mencom.7958
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7958
TI - Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety
T2 - Mendeleev Communications
AU - Limarev, Ilya P.
AU - Lebed, Ekaterina G
AU - Vologzhanina, Anna Vladimirovna
AU - Bugaenko, Margarita Gennad'evna
AU - Voloshin, Yan Zigfridovich
PY - 2026
DA - 2026/03/24
PB - Mendeleev Communications
SP - 282-284
IS - 3
VL - 36
ER -
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@article{2026_Limarev,
author = {Ilya P. Limarev and Ekaterina G Lebed and Anna Vladimirovna Vologzhanina and Margarita Gennad'evna Bugaenko and Yan Zigfridovich Voloshin},
title = {Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7958},
number = {3},
pages = {282--284},
doi = {10.71267/mencom.7958}
}
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Limarev, Ilya P., et al. “Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety.” Mendeleev Communications, vol. 36, no. 3, Mar. 2026, pp. 282-284. https://mendcomm.colab.ws/publications/10.71267/mencom.7958.
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Keywords

clathrochelates
intramolecular cyclization
iron complexes
ligand reactivity
macrocyclic compounds

Abstract

Nucleophilic replacement of chlorine atoms in the bis-α-(benzil dioximate) iron(II) dichloroclathrochelate with o-aminothiophenol as an N,S-dinucleophile afforded a new monoribbed-functionalized cage complex with a six-membered N,S-fusing moiety. The product was characterized by elemental analysis, MALDI-TOF mass, UV-VIS, 1H and 13C{1H} NMR spectra, and by the single-crystal X-ray diffraction.

Funders

Russian Science Foundation
24-13-00230
Ministry of Education and Science of the Russian Federation
075-00276-25-00

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