Keywords
2-(pentafluorophenyl)chromen-4-one
nucleophilic aromatic substitution (SNArF)
organofluorine compounds
photoluminescence
polycarbazole–flavone hybrids
selective mono- and per-substitution
Abstract
The novel mono-, di-, tri-, and pentacarbazolyl-substituted flavones were obtained from 2',3',4',5',6'-pentafluoroflavone and carbazole by varying the conditions of the base-promoted nucleophilic aromatic substitution reaction. The spatial structure of products in crystals was explored using X-ray diffraction analysis. The synthesized mono- and pentacarbazolyl-substituted derivatives showed satisfactory luminescent properties with photoluminescence quantum yield up to 0.42.
Funders
Russian Science Foundation
24-23-00062
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