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Synthesis and photophysical properties of carbazolyl-substituted flavones

Konstantin V Shcherbakov 1
Konstantin V Shcherbakov
Ekaterina Fedorovna Zhilina 1
Ekaterina Fedorovna Zhilina
Evgeny Vadimovich Shchegolkov 1
Evgeny Vadimovich Shchegolkov
Yanina Valer'evna Burgart 1
Yanina Valer'evna Burgart
Viktor Ivanovich Saloutin 1
Viktor Ivanovich Saloutin
1 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620066 Ekaterinburg, Russian Federation
Published 2026-03-24
CommunicationVolume 36, Issue 3, 291-294
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Shcherbakov K. V. et al. Synthesis and photophysical properties of carbazolyl-substituted flavones // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 291-294.
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Shcherbakov K. V., Panova M. A., Zhilina E. F., Shchegolkov E. V., Burgart Y. V., Saloutin V. I. Synthesis and photophysical properties of carbazolyl-substituted flavones // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 291-294.
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TY - JOUR
DO - 10.71267/mencom.7957
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7957
TI - Synthesis and photophysical properties of carbazolyl-substituted flavones
T2 - Mendeleev Communications
AU - Shcherbakov, Konstantin V
AU - Panova, Mariya Alexandrovna
AU - Zhilina, Ekaterina Fedorovna
AU - Shchegolkov, Evgeny Vadimovich
AU - Burgart, Yanina Valer'evna
AU - Saloutin, Viktor Ivanovich
PY - 2026
DA - 2026/03/24
PB - Mendeleev Communications
SP - 291-294
IS - 3
VL - 36
ER -
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@article{2026_Shcherbakov,
author = {Konstantin V Shcherbakov and Mariya Alexandrovna Panova and Ekaterina Fedorovna Zhilina and Evgeny Vadimovich Shchegolkov and Yanina Valer'evna Burgart and Viktor Ivanovich Saloutin},
title = {Synthesis and photophysical properties of carbazolyl-substituted flavones},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7957},
number = {3},
pages = {291--294},
doi = {10.71267/mencom.7957}
}
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Shcherbakov, Konstantin V., et al. “Synthesis and photophysical properties of carbazolyl-substituted flavones.” Mendeleev Communications, vol. 36, no. 3, Mar. 2026, pp. 291-294. https://mendcomm.colab.ws/publications/10.71267/mencom.7957.
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Keywords

2-(pentafluorophenyl)chromen-4-one
nucleophilic aromatic substitution (SNArF)
organofluorine compounds
photoluminescence
polycarbazole–flavone hybrids
selective mono- and per-substitution

Abstract

The novel mono-, di-, tri-, and pentacarbazolyl-substituted flavones were obtained from 2',3',4',5',6'-pentafluoroflavone and carbazole by varying the conditions of the base-promoted nucleophilic aromatic substitution reaction. The spatial structure of products in crystals was explored using X-ray diffraction analysis. The synthesized mono- and pentacarbazolyl-substituted derivatives showed satisfactory luminescent properties with photoluminescence quantum yield up to 0.42.

Funders

Russian Science Foundation
24-23-00062

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