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Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells

Alexander Vasilyevich Prokudin 1
Alexander Vasilyevich Prokudin
, 
Mikhail A Dziuba 1
Mikhail A Dziuba
, 
Valerii Ivanovich Safonov 1
Valerii Ivanovich Safonov
, 
Konstantin V. Deriabin 2
Konstantin V. Deriabin
, 
Anna S. Miroshnichenko 2
Anna S. Miroshnichenko
, 
Regina Maratovna Islamova 2
Regina Maratovna Islamova
, 
Ekaterina Vladimirovna Bartashevich 1
Ekaterina Vladimirovna Bartashevich
, 
10.71267/mencom.7926
Published 2026-03-24
Communication , Volume 36, Issue 3, 308-310
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Prokudin A. V. et al. Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 308-310.
GOST all authors (up to 50) Copy
Prokudin A. V., Dziuba M. A., Safonov V. I., Deriabin K. V., Miroshnichenko A. S., Islamova R. M., Bartashevich E. V., Korzhov A. V. Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells // Mendeleev Communications. 2026. Vol. 36. No. 3. pp. 308-310.
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TY - JOUR
DO - 10.71267/mencom.7926
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7926
TI - Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells
T2 - Mendeleev Communications
AU - Prokudin, Alexander Vasilyevich
AU - Dziuba, Mikhail A
AU - Safonov, Valerii Ivanovich
AU - Deriabin, Konstantin V.
AU - Miroshnichenko, Anna S.
AU - Islamova, Regina Maratovna
AU - Bartashevich, Ekaterina Vladimirovna
AU - Korzhov, Anton Veniaminovich
PY - 2026
DA - 2026/03/24
PB - Mendeleev Communications
SP - 308-310
IS - 3
VL - 36
ER -
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@article{2026_Prokudin,
author = {Alexander Vasilyevich Prokudin and Mikhail A Dziuba and Valerii Ivanovich Safonov and Konstantin V. Deriabin and Anna S. Miroshnichenko and Regina Maratovna Islamova and Ekaterina Vladimirovna Bartashevich and Anton Veniaminovich Korzhov},
title = {Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7926},
number = {3},
pages = {308--310},
doi = {10.71267/mencom.7926}
}
MLA
Cite this
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Prokudin, Alexander Vasilyevich, et al. “Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells.” Mendeleev Communications, vol. 36, no. 3, Mar. 2026, pp. 308-310. https://mendcomm.colab.ws/publications/10.71267/mencom.7926.
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Keywords

electrical breakdown
polysiloxane
self-healing
silicone materials
siloxane equilibrium

Abstract

Self-healing silicone rubber (SHSR) leveraging the ‘siloxane equilibrium’ mechanism was obtained by cross-linking anionic ring-opening copolymerization of octamethylcyclotetrasiloxane (D4) and a pre-synthesized bis-D4 agent using tetramethylammonium hydroxide as an initiator. The new methodology of analysis was developed and the results of dynamics of SHSR self-healing after its low-power breakdown in specially constructed small-volume cells using visual detection of defect evolution over a longtime period are presented.

Funders

Ministry of Education and Science of the Russian Federation
FENU 2024-0003

References

1.
Evolution of self-healing elastomers, from extrinsic to combined intrinsic mechanisms: a review
Utrera-Barrios S., Verdejo R., López-Manchado M.A., Hernández Santana M.
Materials Horizons, 2020
2.
Self-Healing Materials for Electronics Applications
Mashkoor F., Lee S.J., Yi H., Noh S.M., Jeong C.
International Journal of Molecular Sciences, 2022
3.
Self-Healing Silicone Materials: Looking Back and Moving Forward
Deriabin K.V., Filippova S.S., Islamova R.M.
Biomimetics, 2023
4.
Self-healing electrical insulation systems
Basu S., German I., Rhodes R., Stevens G.C.
2016
5.
State of Art Review on Applications and Mechanism of Self-Healing Materials and Structure
Kumar E.K., Patel S.S., Kumar V., Panda S.K., Mahmoud S.R., Balubaid M.
Archives of Computational Methods in Engineering, 2022
6.
Song T., Jiang B., Li Y., Ji Z., Zhou H., Jiang D., Seok I., Murugadoss V., Wen N., Colorado H.
ES Materials & Manufacturing, 2021
8.
Self-Healing Silicones for Outdoor High Voltage Insulation: Mechanism, Applications and Measurements
Kamand F.Z., Mehmood B., Ghunem R., Hassan M.K., El-Hag A., Al-Sulaiti L., Abdala A.
Energies, 2022
9.
Self‐Healing of Electrical Damage in Polymers
Yang Y., Dang Z., Li Q., He J.
Advanced Science, 2020
10.
Self-Healing, High-Permittivity Silicone Dielectric Elastomer
Madsen F.B., Yu L., Skov A.L.
ACS Macro Letters, 2016
11.
Hydraulically amplified self-healing electrostatic actuators with muscle-like performance
Acome E., Mitchell S.K., Morrissey T.G., Emmett M.B., Benjamin C., King M., Radakovitz M., Keplinger C.
Science, 2018
12.
Intrinsic Self-healing Characteristics of Electrical Tree in Silicone Rubber
Yan Z., Long Y., Yang K., Wang S., Zou Y., Li J.
IEEE Transactions on Dielectrics and Electrical Insulation, 2021
13.
Stretchable Self-Healing Polymeric Dielectrics Cross-Linked Through Metal–Ligand Coordination
Rao Y., Chortos A., Pfattner R., Lissel F., Chiu Y., Feig V., Xu J., Kurosawa T., Gu X., Wang C., He M., Chung J.W., Bao Z.
Journal of the American Chemical Society, 2016
14.
Nickel(II)-Polysiloxane “Sandwiches” as Electrical Breakdown Protective Materials
Deriabin K.V., Dziuba M.A., Rashevskii A.A., Kolesnikov I.E., Korzhov A.V., Sharov V.A., Vorobyev A., Vereshchagin A.A., Chernukha A.S., Tian J., Levin O.V., Mukhin I.S., Islamova R.M.
ACS Applied Polymer Materials, 2022
15.
Electrical Trees of Silicone Gel Encapsulation Materials in Power Electronic Modules Self-healing Properties and Influencing Factors
Wang J., Chen C., Yan H., Wang W., Zou L., Zhang L.
IEEE Transactions on Industry Applications, 2024
16.
Makarov G.I., Makarova T.M.
Mendeleev Communications, 2025
21.
Self-Healing Redox-Active Coatings Based on Ferrocenyl-Containing Polysiloxanes
Rashevskii A.A., Deriabin K.V., Parshina E.K., Islamova R.M.
Coatings, 2023
23.
Breakdown Performance Evaluation and Lifetime Prediction of XLPE Insulation in HVAC Cables
Li Z., Dong Y., Wu Y., Meng Z., Song P., Zhu M., Li X., Du B.
Energies, 2024