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Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates

Leonid Alekseevich Kulikov 1
Leonid Alekseevich Kulikov
, 
Elizaveta D. Oskina 1, 2
Elizaveta D. Oskina
, 
Anton L'vovich Maksimov 1, 2
Anton L'vovich Maksimov
, 
Eduard Avetisovich Karakhanov 1
Eduard Avetisovich Karakhanov
10.71267/mencom.7898
Published 2026-02-03
Communication , Volume 36, Issue 2, 220-222
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Kulikov L. A. et al. Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 220-222.
GOST all authors (up to 50) Copy
Kulikov L. A., Oskina E. D., Maksimov A. L., Karakhanov E. A. Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates // Mendeleev Communications. 2026. Vol. 36. No. 2. pp. 220-222.
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TY - JOUR
DO - 10.71267/mencom.7898
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7898
TI - Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates
T2 - Mendeleev Communications
AU - Kulikov, Leonid Alekseevich
AU - Oskina, Elizaveta D.
AU - Maksimov, Anton L'vovich
AU - Karakhanov, Eduard Avetisovich
PY - 2026
DA - 2026/02/03
PB - Mendeleev Communications
SP - 220-222
IS - 2
VL - 36
ER -
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@article{2026_Kulikov,
author = {Leonid Alekseevich Kulikov and Elizaveta D. Oskina and Anton L'vovich Maksimov and Eduard Avetisovich Karakhanov},
title = {Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates},
journal = {Mendeleev Communications},
year = {2026},
volume = {36},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7898},
number = {2},
pages = {220--222},
doi = {10.71267/mencom.7898}
}
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Kulikov, Leonid Alekseevich, et al. “Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates.” Mendeleev Communications, vol. 36, no. 2, Feb. 2026, pp. 220-222. https://mendcomm.colab.ws/publications/10.71267/mencom.7898.

Keywords

hydrogenation
nanoparticles
organic carbonate
palladium catalyst
porous aromatic frameworks

Abstract

Hydrogenation of organic cyclic carbonates using Pd catalysts based on different porous aromatic frameworks was investigated. Under the selected conditions (250 °C, 40 atm of H2), hydrodecarbonylation and hydrodecarboxylation of carbonates occur, with alcohols and diols forming as the main reaction products. The products of complete hydrogenation of ethylene carbonate on the Pd-PAF-30-NH2-pre catalyst were ethanol (yield of 48%), as well as mono-, di- , and triethylene glycols (yields of 28, 17, and 7%, respectively).

Funders

Ministry of Education and Science of the Russian Federation
121031300092-6

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