Home / Publications / Novel copolymers for fibers based on cyclocarbonates and lactide

Novel copolymers for fibers based on cyclocarbonates and lactide

, 
Anna Konstantinovna Berkovich 1
Anna Konstantinovna Berkovich
, 
Polina A Ledneva 1
Polina A Ledneva
,  ,  , 
Artem Nikolaevich Fakhrutdinov 2
Artem Nikolaevich Fakhrutdinov
,  , 
10.71267/mencom.7897
Published 2025-11-29
Communication , Volume 36, Issue 1, 110-113
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Agaeva M. U. K. et al. Novel copolymers for fibers based on cyclocarbonates and lactide // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 110-113.
GOST all authors (up to 50) Copy
Agaeva M. U. K., Berkovich A. K., Ledneva P. A., Serova V. A., Zhirnov A. E., Fakhrutdinov A. N., Mankaev B. N., Karlov S. S. Novel copolymers for fibers based on cyclocarbonates and lactide // Mendeleev Communications. 2025. Vol. 36. No. 1. pp. 110-113.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.71267/mencom.7897
UR - https://mendcomm.colab.ws/publications/10.71267/mencom.7897
TI - Novel copolymers for fibers based on cyclocarbonates and lactide
T2 - Mendeleev Communications
AU - Agaeva, Milana Umud kyzy
AU - Berkovich, Anna Konstantinovna
AU - Ledneva, Polina A
AU - Serova, Valeriia A.
AU - Zhirnov, Artem E
AU - Fakhrutdinov, Artem Nikolaevich
AU - Mankaev, Badma Nikolaevich
AU - Karlov, Sergey Sergeevich
PY - 2025
DA - 2025/11/29
PB - Mendeleev Communications
SP - 110-113
IS - 1
VL - 36
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2025_Agaeva,
author = {Milana Umud kyzy Agaeva and Anna Konstantinovna Berkovich and Polina A Ledneva and Valeriia A. Serova and Artem E Zhirnov and Artem Nikolaevich Fakhrutdinov and Badma Nikolaevich Mankaev and Sergey Sergeevich Karlov},
title = {Novel copolymers for fibers based on cyclocarbonates and lactide},
journal = {Mendeleev Communications},
year = {2025},
volume = {36},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.71267/mencom.7897},
number = {1},
pages = {110--113},
doi = {10.71267/mencom.7897}
}
MLA
Cite this
MLA Copy
Agaeva, Milana Umud kyzy, et al. “Novel copolymers for fibers based on cyclocarbonates and lactide.” Mendeleev Communications, vol. 36, no. 1, Nov. 2025, pp. 110-113. https://mendcomm.colab.ws/publications/10.71267/mencom.7897.
Views
7

Keywords

copolymerization
cyclocarbonates
hydrolytic stability.
L-lactide
polycarbonates
ring-opening polymerization

Abstract

Three cyclocarbonates, namely 1,3-dioxan-2-ones bearing 5-positioned ethyl, butyl and benzyl substituents, were synthesized by the cyclization of ethyl chloroformate with the corresponding propane-1,3-diols. Homopolymers of these cyclocarbonates as well as their copolymers with L-lactide were obtained by ring-opening polymerization using ZnEt2 as the initiator. The prepared homo- and copolymers were found suitable for the production of composite polylactide fibers with tunable hydrophobicity.

Funders

Russian Science Foundation
18-29-17029

References

1.
Production, use, and fate of all plastics ever made
Geyer R., Jambeck J.R., Law K.L.
Science advances, 2017
3.
Recent advances in bone tissue engineering scaffolds
Bose S., Roy M., Bandyopadhyay A.
Trends in Biotechnology, 2012
7.
Synthesis and characterization of novel aliphatic polycarbonates
Wang X., Zhuo R., Liu L., He F., Liu G.
Journal of Polymer Science, Part A: Polymer Chemistry, 2001
8.
Synthesis and Characterization of Novel Glycerol-Derived Polycarbonates with Pendant Hydroxyl Groups
Mei H., Zhong Z., Long F., Zhuo R.
Macromolecular Rapid Communications, 2006
9.
Synthesis and Characterization of Hydroxyl-Functionalized Poly(propylene carbonate)
Wu X., Zhao H., Nörnberg B., Theato P., Luinstra G.A.
Macromolecules, 2014
12.
Synthesis of Polyacids by Copolymerization of l-Lactide with MTC-COOH Using Zn[(acac)(L)H2O] Complex as an Initiator
Jaworska J., Sobota M., Pastusiak M., Kawalec M., Janeczek H., Rychter P., Lewicka K., Dobrzyński P.
Polymers, 2022
16.
Synthesis and characterization of amino-functionalized poly(propylene carbonate)
Song P., Shang Y., Chong S., Zhu X., Xu H., Xiong Y.
RSC Advances, 2015
17.
Fabrication of Biomedical Scaffolds Using Biodegradable Polymers
Kirillova A., Yeazel T.R., Asheghali D., Petersen S.R., Dort S., Gall K., Becker M.L.
Chemical Reviews, 2021
19.
Cyclic carbonates, novel expandable monomers on polymerization
Takata T., Sanda F., Ariga T., Nemoto H., Endo T.
Macromolecular Rapid Communications, 1997
20.
Synthesis, properties, and biodegradation of poly(1,3-trimethylene carbonate)
Zhu K.J., Hendren R.W., Jensen K., Pitt C.G.
Macromolecules, 1991
21.
The Novel Gallium Aminobisphenolate Initiator of the Ring-Opening Copolymerization of L-Lactide and ε-Caprolactone: A Computational Study
Zabalov M.V., Mankaev B.N., Egorov M.P., Karlov S.S.
International Journal of Molecular Sciences, 2022
24.
Unambiguous Determination of the 13C and 1H NMR Stereosequence Assignments of Polylactide Using High-Resolution Solution NMR Spectroscopy
Zell M.T., Padden B.E., Paterick A.J., Thakur K.A., Kean R.T., Hillmyer M.A., Munson E.J.
Macromolecules, 2002
27.
Biodegradable electrospun PLA-PHB fibers plasticized with oligomeric lactic acid
Arrieta M.P., Perdiguero M., Fiori S., Kenny J.M., Peponi L.
Polymer Degradation and Stability, 2020